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LOR 10A process recipe

LOR 10A is the thickest of the slow-dissolving A underlayers at 0.58-1.43 µm, and the grade the datasheet leads with — its Figure 1 shows LOR 10A under a high-temperature negative resist.

https://nanyte.com/photoresists/lor-10a · last updated 2026-09-12

At a glance
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Manufacturer
MicroChem (MCC) — now Kayaku Advanced Materials
Tone
Not photoimageable (underlayer)
Chemistry
Ancillary (not photoimageable)
Thickness
0.6–1.4 µm
Exposure dose
Not exposed — dissolves in developer
Developer
No specific commercial developer product is named for this grade; the datasheet states LOR/PMGI is compatible with both metal-ion-free (TMAH) and metal-ion-bearing developer chemistries.
Applications
Lift-off

Cross-checked — two independent extractions agree on the spin curve and the single-value figures.

The underlayer is never exposed: it sits beneath an imaged top resist and the developer undercuts it laterally, leaving the overhang lift-off relies on. Schematic cross-sections for LOR 10A — feature width, film aspect ratio and sidewall angle are illustrative, not to scale.
01 / Coating

Spin coating

Spin curve for LOR 10A: film thickness in µm against spin speed in rpm.0.40.60.81.01.21.41.61k2k3k4kSPIN SPEED (rpm)THICKNESS (µm)
Data points
LOR 10A — film thickness (µm) by spin speed (rpm)
Seriesrpmµm
LOR 10A10001.4
15001.0
20000.87
25000.72
30000.63
35000.59
40000.58

Values are the manufacturer’s starting points, not a guarantee — characterize on your own tool. Series digitized from a published figure are approximate (±10 %).

read from figure — the green filled-triangle trace legended LOR 10A on the 'Thickness vs. Spin Speed - LOR A Thick Series' chart, p.5. Seven plotted markers at 500 rpm intervals; no numeric table accompanies the chart.

Redrawn from the manufacturer's published data — hover to read between points, click to pin.
  • From 14,300 Å at 1000 rpm the curve falls steeply to about 8,700 Å by 2000 rpm, then flattens hard — 3500 and 4000 rpm differ by only 100 Å.
  • So the usable control range is really 1000-2500 rpm, and targeting much below 0.6 µm means dropping to LOR 7A or 5A rather than spinning faster.
  • Coating parameters are published for the product line rather than per grade: 5 ml dispensed dynamically over 3-5 s onto a 150 mm wafer at 300-500 rpm, 10,000 rpm/s acceleration to a 3,000 rpm terminal speed, 45 s spin, with EBR PG for edge-bead and whisker removal.
Adhesion
HMDS not required — "Primers, such as HMDS, are typically not required" when LOR/PMGI is used as recommended; the datasheet describes excellent adhesion across semiconductor substrates. To dehydrate the surface first, bake at 200 °C for 5 min. LOR/PMGI is virtually insoluble in typical photoresist solvents, so a properly baked underlayer does not intermix with the imaging resist above it.
02 / Bake

Soft bake

Soft bake
Not published — characterize on-tool
Notes
The prebake dries the film and fixes its dissolution and undercut rate, and no grade-specific temperature or time is published. The recommended prebake range for the product line is 160-210 °C, hotplate preferred, and some PMGI products bake as high as 280 °C. Prebake temperature has the greatest influence on undercut rate, with prebake time, developer choice, develop mode and especially develop time behind it. That headroom matters for this grade in particular: the datasheet pairs it with a high-temperature negative resist in its opening figure, and the underlayer has to survive that resist's own bake without its undercut behaviour drifting. The published undercut-versus-bake curves (Figures 5a and 5b) are measured on LOR 10B — same nominal thickness class, faster dissolution — so they give the shape rather than numbers to copy.
SOURCE: "Soft-Bake/Prebake Process" section and Figures 5a-5b, Kayaku…

"Soft-Bake/Prebake Process" section and Figures 5a-5b, Kayaku "LOR and PMGI Resists" technical data sheet, Rev. D (August 2023)

03 / Exposure

Exposure

LOR 10A is not photoimageable. It is not exposed at all — it is coated beneath an imaged top resist and undercut laterally during development. See the development step below.

04 / Development

Development

Developer
No specific commercial developer product is named for this grade; the datasheet states LOR/PMGI is compatible with both metal-ion-free (TMAH) and metal-ion-bearing developer chemistries.
Developer family
TMAH or buffered alkaline

Not published for this resist: Dilution, Time, Method, Rinse — characterize on-tool.

SOURCE: Product description, the LOR/PMGI process-flow section and the…

Product description, the LOR/PMGI process-flow section and the product selection guide, Kayaku "LOR and PMGI Resists" technical data sheet, Rev. D (August 2023)

05 / Post-processing

Hard bake, etch & strip

Stripper
Remover PG. EBR PG removes edge beads and whiskers and is also an effective spin-bowl cleaner and a rework solvent for unbaked wafers.
Storage
Store upright in original sealed containers in a dry area between 4 and 27 °C (40-80 °F), away from ignition sources, light, heat, oxidants, acids and reducers. Do not use after the expiration date.

Not published for this resist: Hard bake, Descum, Etch resistance — characterize on-tool.

06 / Applications

Where it's used

Practical notes from the datasheet

LOR 10A is the thick end of the slow-dissolving A series, a PMGI-based sacrificial film spun beneath a conventional photoresist and never exposed. It is also the grade Kayaku leads the datasheet with: Figure 1 shows LOR 10A used under a high-temperature negative resist, which is the case the A series is built for — a slow underlayer whose undercut opens gradually and predictably, under an imaging resist whose own processing runs hot. Choosing 10A over the same-thickness 10B is not a thickness decision; both land around one micron. It is a decision to take the slower film, trading a wider undercut per unit develop time for a wider process window before the ledge runs too far under a feature. At 0.58-1.43 µm the film is thick enough for substantial metal stacks, and thick enough that prebake temperature and develop time both start to matter more than they do on the sub-micron A grades.

07 / Family

Grades in this family

Other grades in the LOR A series line differ mainly in coating thickness:

LOR A series — grade comparison
GradeThickness
LOR 1A0.1–0.2 µm
LOR 2A0.1–0.3 µm
LOR 3A0.2–0.4 µm
LOR 5A0.3–0.8 µm
LOR 7A0.4–1.1 µm
LOR 10A (this page)0.6–1.4 µm
LOR 15A1.0–2.6 µm
08 / Sources

Sources & disclaimer

Manufacturer datasheet values are starting points; optimal parameters depend on your substrate, equipment and environment. Product names and trademarks belong to their respective owners. NANYTE is not affiliated with the manufacturers listed. Last updated 2026-09-12.

Cite this recipe

NANYTE. "LOR 10A process recipe." NANYTE Photoresist Library. https://nanyte.com/photoresists/lor-10a. Accessed 2026-09-12.

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