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LOR 1A process recipe

LOR 1A is the thinnest underlayer in the LOR line at 0.081-0.158 µm, for lift-off of thin metal where anything thicker would swallow the feature.

https://nanyte.com/photoresists/lor-1a · last updated 2026-09-12

At a glance
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Manufacturer
MicroChem (MCC) — now Kayaku Advanced Materials
Tone
Not photoimageable (underlayer)
Chemistry
Ancillary (not photoimageable)
Thickness
0.1–0.2 µm
Exposure dose
Not exposed — dissolves in developer
Developer
No specific commercial developer product is named for this grade; the datasheet states LOR/PMGI is compatible with both metal-ion-free (TMAH) and metal-ion-bearing developer chemistries.
Applications
Lift-off

Cross-checked — two independent extractions agree on the spin curve and the single-value figures.

The underlayer is never exposed: it sits beneath an imaged top resist and the developer undercuts it laterally, leaving the overhang lift-off relies on. Schematic cross-sections for LOR 1A — feature width, film aspect ratio and sidewall angle are illustrative, not to scale.
01 / Coating

Spin coating

Spin curve for LOR 1A: film thickness in µm against spin speed in rpm.0.060.080.100.120.140.160.181k2k3k4kSPIN SPEED (rpm)THICKNESS (µm)
Data points
LOR 1A — film thickness (µm) by spin speed (rpm)
Seriesrpmµm
LOR 1A10000.16
15000.12
20000.10
25000.10
30000.09
35000.08
40000.08

Values are the manufacturer’s starting points, not a guarantee — characterize on your own tool. Series digitized from a published figure are approximate (±10 %).

read from figure — the blue filled-diamond trace legended LOR 1A on the 'Thickness vs. Spin Speed - LOR A Thin Series' chart, p.5, the lowest of the three traces. Seven plotted markers at 500 rpm intervals; no numeric table accompanies the chart.

Redrawn from the manufacturer's published data — hover to read between points, click to pin.
  • The whole grade lives between 810 and 1,580 Å, so the entire spin sweep buys under 80 nm of thickness and the curve is flat from about 2500 rpm onward.
  • Spin speed is a trim here, not a control — pick the grade for the thickness you want and use speed to fine-tune.
  • Coating parameters are published for the product line rather than per grade: 5 ml dispensed dynamically over 3-5 s onto a 150 mm wafer at 300-500 rpm, 10,000 rpm/s acceleration to a 3,000 rpm terminal speed, 45 s spin, with EBR PG for edge-bead and whisker removal.
Adhesion
HMDS not required — "Primers, such as HMDS, are typically not required" when LOR/PMGI is used as recommended; the datasheet describes excellent adhesion across semiconductor substrates. To dehydrate the surface first, bake at 200 °C for 5 min. LOR/PMGI is virtually insoluble in typical photoresist solvents, so a properly baked underlayer does not intermix with the imaging resist above it.
02 / Bake

Soft bake

Soft bake
Not published — characterize on-tool
Notes
The prebake dries the film and fixes its dissolution and undercut rate, and no grade-specific temperature or time is published. The recommended prebake range for the product line is 160-210 °C, hotplate preferred, and some PMGI products bake as high as 280 °C. Prebake temperature has the greatest influence on undercut rate, with prebake time, developer choice, develop mode and especially develop time behind it. Hotter and longer both slow the dissolution and tighten the undercut. The published undercut-versus-bake curves (Figures 5a and 5b) are measured on LOR 10B, a B-series grade an order of magnitude thicker than this one, so they show the shape of the relationship rather than numbers to transfer here.
SOURCE: "Soft-Bake/Prebake Process" section and Figures 5a-5b, Kayaku…

"Soft-Bake/Prebake Process" section and Figures 5a-5b, Kayaku "LOR and PMGI Resists" technical data sheet, Rev. D (August 2023)

03 / Exposure

Exposure

LOR 1A is not photoimageable. It is not exposed at all — it is coated beneath an imaged top resist and undercut laterally during development. See the development step below.

04 / Development

Development

Developer
No specific commercial developer product is named for this grade; the datasheet states LOR/PMGI is compatible with both metal-ion-free (TMAH) and metal-ion-bearing developer chemistries.
Developer family
TMAH or buffered alkaline

Not published for this resist: Dilution, Time, Method, Rinse — characterize on-tool.

SOURCE: Product description, the LOR/PMGI process-flow section and the…

Product description, the LOR/PMGI process-flow section and the product selection guide, Kayaku "LOR and PMGI Resists" technical data sheet, Rev. D (August 2023)

05 / Post-processing

Hard bake, etch & strip

Stripper
Remover PG. EBR PG removes edge beads and whiskers and is also an effective spin-bowl cleaner and a rework solvent for unbaked wafers.
Storage
Store upright in original sealed containers in a dry area between 4 and 27 °C (40-80 °F), away from ignition sources, light, heat, oxidants, acids and reducers. Do not use after the expiration date.

Not published for this resist: Hard bake, Descum, Etch resistance — characterize on-tool.

06 / Applications

Where it's used

Practical notes from the datasheet

LOR 1A is the thin end of the whole LOR range — a PMGI-based sacrificial film spun under a conventional photoresist and never exposed itself. At 810 to 1,580 Å it is thinner than most of the metal anyone lifts off with it, which is the point rather than a limitation: the underlayer only has to out-dissolve the imaging resist far enough to break the deposited film at its edge, and every extra nanometre of sacrificial layer costs resolution. That makes this the grade for fine features and thin depositions, where a micron-scale underlayer would undercut straight through the pattern. The A series dissolves more slowly than B or C for the same prebake, which is the other half of why it suits fine work — the ledge opens gradually and the process window is wider. Nothing here is exposed, so there is no dose, no tone and no post-exposure bake to set; prebake temperature and develop time do all the work.

07 / Family

Grades in this family

Other grades in the LOR A series line differ mainly in coating thickness:

LOR A series — grade comparison
GradeThickness
LOR 1A (this page)0.1–0.2 µm
LOR 2A0.1–0.3 µm
LOR 3A0.2–0.4 µm
LOR 5A0.3–0.8 µm
LOR 7A0.4–1.1 µm
LOR 10A0.6–1.4 µm
LOR 15A1.0–2.6 µm
08 / Sources

Sources & disclaimer

Manufacturer datasheet values are starting points; optimal parameters depend on your substrate, equipment and environment. Product names and trademarks belong to their respective owners. NANYTE is not affiliated with the manufacturers listed. Last updated 2026-09-12.

Cite this recipe

NANYTE. "LOR 1A process recipe." NANYTE Photoresist Library. https://nanyte.com/photoresists/lor-1a. Accessed 2026-09-12.

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