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LOR 2A process recipe

LOR 2A sits between LOR 1A and LOR 3A in the slow-dissolving A series, coating 0.128-0.265 µm for lift-off of thin films where 1A is too thin to break the deposit and 3A undercuts too far.

https://nanyte.com/photoresists/lor-2a · last updated 2026-09-12

At a glance
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Manufacturer
MicroChem (MCC) — now Kayaku Advanced Materials
Tone
Not photoimageable (underlayer)
Chemistry
Ancillary (not photoimageable)
Thickness
0.1–0.3 µm
Exposure dose
Not exposed — dissolves in developer
Developer
No specific commercial developer product is named for this grade; the datasheet states LOR/PMGI is compatible with both metal-ion-free (TMAH) and metal-ion-bearing developer chemistries.
Applications
Lift-off

Cross-checked — two independent extractions agree on the spin curve and the single-value figures.

The underlayer is never exposed: it sits beneath an imaged top resist and the developer undercuts it laterally, leaving the overhang lift-off relies on. Schematic cross-sections for LOR 2A — feature width, film aspect ratio and sidewall angle are illustrative, not to scale.
01 / Coating

Spin coating

Spin curve for LOR 2A: film thickness in µm against spin speed in rpm.0.100.150.200.250.301k2k3k4kSPIN SPEED (rpm)THICKNESS (µm)
Data points
LOR 2A — film thickness (µm) by spin speed (rpm)
Seriesrpmµm
LOR 2A10000.27
15000.20
20000.18
25000.16
30000.15
35000.14
40000.13

Values are the manufacturer’s starting points, not a guarantee — characterize on your own tool. Series digitized from a published figure are approximate (±10 %).

read from figure — the red filled-square trace legended LOR 2A on the 'Thickness vs. Spin Speed - LOR A Thin Series' chart, p.5, the middle of the three traces. Seven plotted markers at 500 rpm intervals; no numeric table accompanies the chart.

Redrawn from the manufacturer's published data — hover to read between points, click to pin.
  • A shallow curve across the whole sweep — 2,650 Å at 1000 rpm to 1,280 Å at 4000 — so the grade spans barely a factor of two and speed is a fine trim rather than a coarse control.
  • It tracks roughly midway between the 1A and 3A traces at every speed, which is the practical way to place it: if a target falls between those two grades' ranges, this is the grade rather than a spin-speed compromise on either.
  • Coating parameters are published for the product line rather than per grade: 5 ml dispensed dynamically over 3-5 s onto a 150 mm wafer at 300-500 rpm, 10,000 rpm/s acceleration to a 3,000 rpm terminal speed, 45 s spin, with EBR PG for edge-bead and whisker removal.
Adhesion
HMDS not required — "Primers, such as HMDS, are typically not required" when LOR/PMGI is used as recommended; the datasheet describes excellent adhesion across semiconductor substrates. To dehydrate the surface first, bake at 200 °C for 5 min. LOR/PMGI is virtually insoluble in typical photoresist solvents, so a properly baked underlayer does not intermix with the imaging resist above it.
02 / Bake

Soft bake

Soft bake
Not published — characterize on-tool
Notes
The prebake dries the film and fixes its dissolution and undercut rate, and no grade-specific temperature or time is published. The recommended prebake range for the product line is 160-210 °C, hotplate preferred, and some PMGI products bake as high as 280 °C. Prebake temperature has the greatest influence on undercut rate, with prebake time, developer choice, develop mode and especially develop time behind it. The published undercut-versus-bake curves (Figures 5a and 5b) are measured on LOR 10B, a faster B-series grade several times thicker, so they show the shape of the relationship rather than numbers to transfer here.
SOURCE: "Soft-Bake/Prebake Process" section and Figures 5a-5b, Kayaku…

"Soft-Bake/Prebake Process" section and Figures 5a-5b, Kayaku "LOR and PMGI Resists" technical data sheet, Rev. D (August 2023)

03 / Exposure

Exposure

LOR 2A is not photoimageable. It is not exposed at all — it is coated beneath an imaged top resist and undercut laterally during development. See the development step below.

04 / Development

Development

Developer
No specific commercial developer product is named for this grade; the datasheet states LOR/PMGI is compatible with both metal-ion-free (TMAH) and metal-ion-bearing developer chemistries.
Developer family
TMAH or buffered alkaline

Not published for this resist: Dilution, Time, Method, Rinse — characterize on-tool.

SOURCE: Product description, the LOR/PMGI process-flow section and the…

Product description, the LOR/PMGI process-flow section and the product selection guide, Kayaku "LOR and PMGI Resists" technical data sheet, Rev. D (August 2023)

05 / Post-processing

Hard bake, etch & strip

Stripper
Remover PG. EBR PG removes edge beads and whiskers and is also an effective spin-bowl cleaner and a rework solvent for unbaked wafers.
Storage
Store upright in original sealed containers in a dry area between 4 and 27 °C (40-80 °F), away from ignition sources, light, heat, oxidants, acids and reducers. Do not use after the expiration date.

Not published for this resist: Hard bake, Descum, Etch resistance — characterize on-tool.

06 / Applications

Where it's used

Practical notes from the datasheet

LOR 2A is a PMGI-based sacrificial underlayer from the slow-dissolving A series, spun beneath a conventional photoresist and never exposed itself. Its job is purely geometric: the underlayer has to out-dissolve the imaging resist far enough that the metal landing on the substrate and the metal landing on top of the resist never join, and it has to do that without the ledge running so far under the pattern that fine features collapse. At 0.128-0.265 µm this grade is aimed at thin depositions — thin enough that LOR 1A cannot reliably break the film, thick enough that LOR 3A would be generous. The A series is the slower of the three dissolution families, which widens the process window at the cost of needing a cooler or longer develop to reach the same undercut. Nothing here is exposed, so there is no dose, no tone and no post-exposure bake; prebake temperature and develop time do all the work.

07 / Family

Grades in this family

Other grades in the LOR A series line differ mainly in coating thickness:

LOR A series — grade comparison
GradeThickness
LOR 1A0.1–0.2 µm
LOR 2A (this page)0.1–0.3 µm
LOR 3A0.2–0.4 µm
LOR 5A0.3–0.8 µm
LOR 7A0.4–1.1 µm
LOR 10A0.6–1.4 µm
LOR 15A1.0–2.6 µm
08 / Sources

Sources & disclaimer

Manufacturer datasheet values are starting points; optimal parameters depend on your substrate, equipment and environment. Product names and trademarks belong to their respective owners. NANYTE is not affiliated with the manufacturers listed. Last updated 2026-09-12.

Cite this recipe

NANYTE. "LOR 2A process recipe." NANYTE Photoresist Library. https://nanyte.com/photoresists/lor-2a. Accessed 2026-09-12.

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