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KMPR 1025 process recipe

KMPR 1025 covers 21.5-87 µm in a single coat, the band where copper pillar plating and deep DRIE masks live — and the grade whose thick end runs past the edge of the datasheet's own process tables.

https://nanyte.com/photoresists/kmpr-1025 · last updated 2026-09-12

At a glance
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Manufacturer
Kayaku Advanced Materials
Tone
negative
Chemistry
Epoxy (SU-8 type)
Thickness
21.5–87 µm
Developer
2.38 % TMAH (0.26 N) aqueous alkaline developer; SU-8 developer (solvent) may be used instead
Applications
High aspect ratio · MEMS structural · Electroplating / molding · Etch mask

Cross-checked — two independent extractions agree on the spin curve and the single-value figures.

The exposed resist stays after development; the unexposed film dissolves. Schematic cross-sections for KMPR 1025 — feature width, film aspect ratio and sidewall angle are illustrative, not to scale.
01 / Coating

Spin coating

Spin curve for KMPR 1025: film thickness in µm against spin speed in rpm.0204060801001k2k3k4kSPIN SPEED (rpm)THICKNESS (µm)
Data points
KMPR 1025 — film thickness (µm) by spin speed (rpm)
SeriesrpmµmPublished dose
KMPR 1025100087
200043
665–1055 mJ/cm² · 31–55 µm row
300029
500–645 mJ/cm² · 21–30 µm row
665–1055 mJ/cm² · 31–55 µm row
within 10 % of a bracket edge
400022
500–645 mJ/cm² · 21–30 µm row
within 10 % of a bracket edge

Values are the manufacturer’s starting points, not a guarantee — characterize on your own tool. Series digitized from a published figure are approximate (±10 %).

Published dose is the datasheet’s own thickness bracket, quoted as printed — the full table and its citation are in the exposure section. A thickness the table does not cover shows nothing, and a thickness within 10 % of a bracket edge shows every bracket it could fall in.

read from figure — the filled-diamond trace legended KMPR 1025 on Figure 1, 'KMPR 1000 Thickness vs. Spin Speed', p.2, the second-highest of the five traces. Four plotted markers; no numeric table accompanies the chart.

Redrawn from the manufacturer's published data — hover to read between points, click to pin.
  • The steepest useful trace on the chart: 87 µm at 1000 rpm halves to 42.5 µm by 2000 rpm, then falls to 28.5 and 21.5 µm.
  • Thickness is therefore very sensitive to speed at the slow end, and a target above about 60 µm is worth confirming on a test wafer rather than reading off the curve.
  • Table 1 puts this grade at 64 % solids and 5200 cSt.
  • The recommended program is a 500 rpm / 5-10 s spread at 100 rpm/s acceleration, then 30 s at the final speed at 300 rpm/s, dispensing 1 ml of resist per inch of substrate diameter.
Adhesion
HMDS recommended — Adhesion promoters are described as typically unnecessary; substrates should be clean and dry, ideally after a piranha clean and a de-ionized water rinse, or an O2 RIE/barrel-asher clean. HMDS priming is recommended specifically where the film will be used for electroplating.
02 / Bake

Soft bake

Soft bake
100 °C (95–105 °C) · hotplate
Notes
100 °C on a level hotplate, with 95-105 °C also usable. Convection ovens are advised against — a skin forms and traps solvent in the film. Time is thickness-binned and this grade spans three of those bins: 12 min for 21-30 µm, 15 min for 31-55 µm and 20 min for 56-80 µm. Above 80 µm the table stops, so the top of this grade's coating range has no published bake time. Bake, cool to room temperature, then return the wafer to the hotplate — visible wrinkling means it needs longer, and at these thicknesses that check is worth doing on every new target.

SOURCE: Soft Bake section and Table 2, p.2 of the KMPR 1000 datasheet (Ver. 6, December 2019)

03 / Exposure

Exposure dose

KMPR 1025's dose is published against film thickness, not as a single number. Read the row for the film you coat and run a dose array around it.

As published
Dose follows the coating rather than the grade, and across this grade's range that is a three-fold spread: 500-645 mJ/cm² at 21-30 µm rising to 1070-1465 mJ/cm² at 56-80 µm, with nothing published above 80 µm. Reflective substrates cost more again — the datasheet's multipliers are 1.5× on glass, Pyrex and ITO and 1.5-2× on gold, aluminium, copper, nickel and titanium against 1× on silicon, which matters here because plating work usually means a metal seed layer.
Post-exposure bake
100 °C (95–105 °C) · hotplate
KMPR 1025 — dose by film thickness
Film thicknessDose
21–30 µm500–645 mJ/cm²
31–55 µm665–1055 mJ/cm²
56–80 µm1070–1465 mJ/cm²
SOURCE: KMPR 1000 datasheet

Table 3 'Exposure Dose' of the KMPR 1000 datasheet (Ver. 6). The three bins carried here are the ones this grade's thickness range crosses; the table's top bin ends at 80 µm, below the 87 µm this grade reaches at 1000 rpm. The table is not attributed to a specific wavelength.

04 / Development

Development

Developer
2.38 % TMAH (0.26 N) aqueous alkaline developer; SU-8 developer (solvent) may be used instead
Method
immersion, spray or spray-puddle
Rinse
After TMAH, spray rinse with de-ionized water for 20 s and blow dry with filtered air or nitrogen. After SU-8 developer, spray with fresh developer for about 10 s, then isopropyl alcohol for another 10 s, then blow dry — a white film during the IPA rinse means the film is under-developed and needs more developer.
Developer family
TMAH or solvent

Not published for this resist: Dilution, Time — characterize on-tool.

SOURCE: Development and Rinse and Dry sections with Tables 6 and 7, p.3-4 of the KMPR 1000 datasheet (Ver. 6, December 2019)

05 / Post-processing

Hard bake, etch & strip

Hard bake
Not published — characterize on-tool
Descum
RIE, 2 min at 100 W with 10 sccm O2 at 100 mTorr — quoted as step 3 of the datasheet's plating sequence.
Etch resistance
"Excellent dry etch resistance" (Features, p.1); the series is positioned for DRIE work, and the datasheet's own example shows 10 µm features etched to 65 µm deep.
Stripper
Remover PG (NMP) at 80 °C for 10-20 min by immersion, provided the film was never hard baked — at this thickness expect the longer end, and ultrasound helps. Plasma removal where needed: RIE at 200 W with 80 sccm O2 and 8 sccm CF4, 100 mTorr, 10 °C.
Storage
Store frozen at -10 °C (14 °F) in tightly closed upright containers, away from light, heat, acids and ignition sources. Shelf life is thirteen months frozen, typically one to two months at room temperature. Defrost at room temperature for 24 h before use.
06 / Applications

Where it's used

Practical notes from the datasheet

KMPR 1025 sits in the tens-of-microns band of Kayaku's chemically amplified epoxy negative series — thick enough for copper pillar moulds and deep etch masks, and the grade the datasheet's own plating example is built around. What changes at this thickness is that every process number stretches: the soft bake runs 12 to 20 minutes depending on where in the range you coat, the clearing dose spans 500 to 1465 mJ/cm², and TMAH development takes 6 to 8 minutes rather than the 3 a thin film needs. None of those are grade properties; they are thickness properties, and the datasheet tabulates them that way. Worth knowing before working at the thick end: the spin curve reaches 87 µm at 1000 rpm, but the soft-bake, dose and develop tables all stop at 80 µm, so the top of this grade's coating range has no published process at all and has to be characterised on-tool. Two other cautions carry weight here. Reflective substrates raise the dose by 1.5-2×, and plating work almost always means a metal seed layer, so a dose set on bare silicon will under-expose on copper. And hard baking is explicitly not recommended for plating resistance — an un-hard-baked film swells and lifts cleanly in Remover PG at 80 °C, while a baked one fights removal at exactly the thickness where removal is already slowest.

07 / Family

Grades in this family

Other grades in the KMPR 1000 series line differ mainly in coating thickness:

KMPR 1000 series — grade comparison
GradeThickness
KMPR 10054.5–9.5 µm
KMPR 101010–27 µm
KMPR 101512.5–40 µm
KMPR 1025 (this page)21.5–87 µm
KMPR 103528–115 µm
KMPR 105034–115 µm
08 / Sources

Sources & disclaimer

Manufacturer datasheet values are starting points; optimal parameters depend on your substrate, equipment and environment. Product names and trademarks belong to their respective owners. NANYTE is not affiliated with the manufacturers listed. Last updated 2026-09-12.

Cite this recipe

NANYTE. "KMPR 1025 process recipe." NANYTE Photoresist Library. https://nanyte.com/photoresists/kmpr-1025. Accessed 2026-09-12.

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