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KMPR 1050 process recipe

KMPR 1050 is the highest-viscosity grade of Kayaku Microchem/MicroChem's KMPR 1000 series, a chemically amplified, TMAH-developable, epoxy-based negative photoresist built for thick, high-aspect-ratio MEMS, electroplating-mold, and DRIE-mask structures.

https://nanyte.com/photoresists/kmpr-1050 · last updated 2026-07-12

At a glance
Manufacturer
Kayaku Microchem (MicroChem)
Tone
negative
Chemistry
Epoxy (SU-8 type)
Thickness
34–115 µm
Developer
2.38% TMAH (0.26N) aqueous alkaline developer (primary); SU-8 Developer (solvent-based) is also usable as an alternative
Applications
High aspect ratio · MEMS structural · Electroplating / molding · Etch mask
Etch maskSuitable for

Cross-checked — two independent extractions agree.

01 / Coating

Spin coating

KMPR 1050 is spin-coated to 34–115 µm. The curve below is redrawn from the manufacturer's published data — read your target thickness off the vertical axis and take the matching spin speed as a starting point.

Spin curves for KMPR 1050: film thickness in µm against spin speed in rpm.0.00501001502001k2k3k4kSPIN SPEED (rpm)THICKNESS (µm)
Data points
KMPR 1050 — film thickness (µm) by spin speed (rpm)
Seriesrpmµm
KMPR 10501000101
200068
300051
400044
KMPR 1050 (23°C Japan & Asia)1000115
200067
300047
400034

Values are the manufacturer's starting points, not a guarantee; verify on your own tool. Characterize on-tool. Series digitized from a published figure were independently cross-checked by a second blind read; treat those values as approximate (±10 %).

KMPR 1050: read from figure 1 "Spin speed vs. Thickness for KMPR 1000 resists (21°C US & EU)", p.2 of the Kayaku Microchem/MicroChem "KMPR 1000 Chemically Amplified Negative Photoresist" datasheet (Ver. 4.2, UPenn nanoSOP mirror). Chart plots four curves (KMPR 1050/filled square, 1025/filled diamond, 1010/filled circle, 1005/open square), each with 4 markers at 1000/2000/3000/4000 rpm. The KMPR 1050 curve was identified as the filled-square series and the topmost (thickest-film) curve at every rpm, consistent with its legend position (listed first) and Table 1's viscosity ordering (1050 = 13,000 cSt, the highest of the four, so it should coat thickest at a given speed). Read at high resolution (4x page render, cropped) so the four data-point markers were individually resolvable; still an eyeball figure read, not a numeric table.

KMPR 1050 (23°C Japan & Asia): read from figure 2 "Spin speed vs. Thickness for KMPR® 1000 resists (23°C Japan & Asia)", p.2 of the Kayaku Microchem/MicroChem "KMPR 1000 Chemically Amplified Negative Photoresist" datasheet (Ver. 4.2, UPenn nanoSOP mirror). Chart plots four curves (KMPR 1050/filled square, 1025/filled diamond, 1010/filled circle, 1005/open square), each with 4 markers at 1000/2000/3000/4000 rpm. The KMPR 1050 curve was identified as the filled-square series and the topmost (thickest-film) curve at every rpm, consistent with its legend position (listed first) and Table 1's viscosity ordering (1050 = 13,000 cSt, the highest of the four). Points were read by extracting the marker vector-path pixel rectangles and the axis tick-label pixel positions directly from the PDF page content stream (not a manual on-screen eyeball estimate), then converting via the resulting pixel-to-value linear scale (0-120 µm y-axis span; 1000 rpm x-axis grid spacing); cross-checked against the rendered chart image (kmpr-1050-p2-hires.png). digitized 2026-07-12

2 series redrawn from the manufacturer's published data — hover to read values between points, click to pin.

Recommended program: dispense 1 ml of resist per inch (25 mm) of substrate diameter; spin at 500 rpm for 5-10 s at 100 rpm/s acceleration, then spin at the target speed for 30 s at 300 rpm/s acceleration. The document publishes TWO spin curves for the same four resists at two different ambient conditions: Figure 1 (21°C, US & EU) and Figure 2 (23°C, Japan & Asia) — the curves are not identical (e.g. KMPR 1050 at 1000 rpm reads ~101 µm in Figure 1 vs. ~115 µm in Figure 2), a reminder that spin results are sensitive to coat-bowl ambient temperature/humidity and should be recharacterized on-tool. Both curves are now captured above: Figure 1 (21°C US & EU) as the primary curve, Figure 2 (23°C Japan & Asia) as a second series digitized by extracting marker vector-path pixel positions and axis tick-label pixel positions directly from the PDF page content stream. Source: "Coat" / "Recommended Program", p.1, and Figures 1-2, p.2.

Adhesion
HMDS not required — "Adhesion promoters are typically not required." HMDS pretreatment (MCC Primer 80/20) is recommended "for applications that require electroplating" — and the document's own Plating process recipe lists HMDS as its first step. Source: "Substrate Preparation", p.1, and "Plating", p.3.
02 / Bake

Soft bake

Soft bake
100 °C · hotplate
Notes
Recommended bake temperature is 100°C (95-105°C also usable, per text) — this scalar temperature is explicit in the document. Time is published as a THICKNESS-BINNED table only up to 80 µm: 5-11 µm → 5 min; 12-20 µm → 7 min; 21-30 µm → 12 min; 31-55 µm → 15 min; 56-80 µm → 20 min. KMPR 1050's own spin curve (Figure 1) reaches 101 µm at 1000 rpm, i.e. above the table's published range — the datasheet does not give a soft-bake time for film thicker than 80 µm at all, so no time is assumed for the thick end of this grade's range. Convection ovens are explicitly not recommended. A cool-down/re-heat 'wrinkle' check is described to confirm the film is fully dry.

SOURCE: Table 2 "Soft Bake Times" and "Soft Bake" section text, p.2

03 / Exposure

Exposure dose

The manufacturer does not publish a clearing dose for KMPR 1050. Determine it with a dose array on your own tool.

As published
"KMPR® 1000 is most commonly exposed with conventional UV (350-400 nm) radiation, although i-line (365 nm) is recommended. It may also be exposed with e-beam or x-ray radiation." (Processing Guidelines, p.1); the front-page banner separately calls the product a "KMPR®1000 i-Line photoresist." The dose table (Table 3) is not separately re-attributed to a specific wavelength beyond this general statement.
Post-exposure bake
100 °C

Not published for this resist: Dose at 365 nm, Dose at 405 nm — characterize on-tool.

04 / Development

Development

Developer
2.38% TMAH (0.26N) aqueous alkaline developer (primary); SU-8 Developer (solvent-based) is also usable as an alternative
Dilution
2.38% TMAH (0.26N), used at this standard concentration (not diluted from a stock in the document)
Time
Not published — characterize on-tool
Method
immersion
Rinse
DI water, ~20 s spray rinse, then filtered air/N2 dry (TMAH path). If the optional SU-8-developer alternative is used instead, rinse is ~10 s fresh developer spray then ~10 s IPA spray, per the SU-8-developer note.
Developer family
TMAH-based

SOURCE: "Develop" and "Rinse and Dry" sections plus Table 5 (TMAH) and Table 6 (SU-8 developer), p.3

05 / Post-processing

Hard bake, etch & strip

Etch resistance
Listed as a Feature: "Excellent dry etch resistance." Demonstrated in an application photo ("Etched Trenches", 10 µm features, 65 µm deep, credited to ULVAC) consistent with use as a DRIE (deep reactive ion etch) mask. No quantitative etch rate or selectivity numbers are published. Source: "Features" list and application photos, p.1.
Stripper
MicroChem Remover PG (NMP): heat bath to 80°C, immerse substrate 10-20 minutes (actual time depends on resist thickness and agitation, e.g. ultrasound). For fully electroformed metal structures, a stronger sequence is given: Remover PG 10 min @80°C → DIW rinse → XP Remover K (epoxy stripping chemistry) 10 min @80°C → DIW rinse → XP Neutralizer K 3 min @25°C. Plasma removal: RIE 200 W, 80 sccm O2, 8 sccm CF4, 100 mTorr, 10°C. Source: "Removal" / "Process Recommendation" / "Plasma Removal", p.3.
Storage
Store frozen, in tightly closed, upright containers, at 14°F (-10°C), away from light, heat, acids, and ignition sources. Shelf life is twelve months at 14°F (-10°C), but typically only one to two months at room temperature. Defrost at room temperature for 24 hours before use. Source: "Storage", p.4.

Not published for this resist: Hard bake, Descum — characterize on-tool.

SOURCE: "Plating" section note, p.3

06 / Applications

Where it's used

High aspect ratioMEMS structuralElectroplating / moldingEtch mask

KMPR 1050 is the thickest-coating grade in Kayaku Microchem/MicroChem's KMPR 1000 line and, unlike the solvent-developed SU-8 2000 family, is a chemically amplified epoxy resist designed to develop in aqueous TMAH — a meaningful process difference worth flagging for anyone assuming all thick epoxy negative resists behave like SU-8. Its published process tables (soft bake, exposure dose, TMAH develop time) only cover film thicknesses up to 80 µm, while KMPR 1050's own spin curve reaches roughly 101 µm at 1000 rpm; process engineers working at the thick end of this grade's range will need to extrapolate or characterize on-tool, since the datasheet simply does not publish numbers there. PEB time follows a thickness-threshold rule (2/3/4 minutes at 25/50 µm cutoffs) rather than a continuous table. A distinctive storage gotcha: KMPR 1000 resists must be stored frozen (14°F/-10°C) and require a full 24-hour room-temperature thaw before use — treating it like a room-temperature-stable resist will produce inconsistent films. The resist strips cleanly with Remover PG when only lightly cross-linked, but a fully electroformed/plated structure needs the stronger Remover PG → XP Remover K → XP Neutralizer K sequence to fully dissolve.

07 / Sources

Sources & disclaimer

Research using this resist
  1. Lee et al.. Fabrication of thick electroforming micro mould using a KMPR negative tone photoresist. Journal of Micromechanics and Microengineering (2008). doi:10.1088/0960-1317/18/5/055032
    180 µm, 18:1 KMPR molds — strippable, unlike SU-8.
  2. Shin et al.. UV Lithography and Molding Fabrication of Ultrathick Micrometallic Structures Using a KMPR Photoresist. Journal of Microelectromechanical Systems (2010). doi:10.1109/JMEMS.2010.2045880
    KMPR molds for mm-wave traveling-wave-tube structures.

Manufacturer datasheet values are starting points; optimal parameters depend on your substrate, equipment and environment. Product names and trademarks belong to their respective owners. NANYTE is not affiliated with the manufacturers listed. Last updated 2026-07-12.

Cite this recipe

NANYTE. "KMPR 1050 process recipe." NANYTE Photoresist Library. https://nanyte.com/photoresists/kmpr-1050. Accessed 2026-07-12.

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