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KMPR 1050 process recipe

KMPR 1050 is the highest-viscosity grade of Kayaku Microchem/MicroChem's KMPR 1000 series, a chemically amplified, TMAH-developable, epoxy-based negative photoresist built for thick, high-aspect-ratio MEMS, electroplating-mold, and DRIE-mask structures.

https://nanyte.com/photoresists/kmpr-1050 · last updated 2026-07-26

At a glance
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Manufacturer
Kayaku Microchem (MicroChem)
Tone
negative
Chemistry
Epoxy (SU-8 type)
Thickness
34–115 µm
Developer
2.38% TMAH (0.26N) aqueous alkaline developer (primary); SU-8 Developer (solvent-based) is also usable as an alternative
Applications
High aspect ratio · MEMS structural · Electroplating / molding · Etch mask

Cross-checked — two independent extractions agree on the spin curve and the single-value figures.

The exposed resist stays after development; the unexposed film dissolves. Schematic cross-sections for KMPR 1050 — feature width, film aspect ratio and sidewall angle are illustrative, not to scale.
01 / Coating

Spin coating

Spin curves for KMPR 1050: film thickness in µm against spin speed in rpm.204060801001201401k2k3k4kSPIN SPEED (rpm)THICKNESS (µm)
Data points
KMPR 1050 — film thickness (µm) by spin speed (rpm)
SeriesrpmµmPublished dose
KMPR 10501000101
200068
1070–1465 mJ/cm² · 56–80 µm row
300051
665–1055 mJ/cm² · 31–55 µm row
1070–1465 mJ/cm² · 56–80 µm row
within 10 % of a bracket edge
400044
665–1055 mJ/cm² · 31–55 µm row
KMPR 1050 (23°C Japan & Asia)1000115
200067
1070–1465 mJ/cm² · 56–80 µm row
300047
665–1055 mJ/cm² · 31–55 µm row
400034
665–1055 mJ/cm² · 31–55 µm row
within 10 % of a bracket edge

Values are the manufacturer’s starting points, not a guarantee — characterize on your own tool. Series digitized from a published figure are approximate (±10 %).

Published dose is the datasheet’s own thickness bracket, quoted as printed — the full table and its citation are in the exposure section. A thickness the table does not cover shows nothing, and a thickness within 10 % of a bracket edge shows every bracket it could fall in.

KMPR 1050: read from figure 1 "Spin speed vs. Thickness for KMPR 1000 resists (21°C US & EU)", p.2 of the Kayaku Microchem/MicroChem "KMPR 1000 Chemically Amplified Negative Photoresist" datasheet (Ver. 4.2, UPenn nanoSOP mirror). Chart plots four curves (KMPR 1050/filled square, 1025/filled diamond, 1010/filled circle, 1005/open square), each with 4 markers at 1000/2000/3000/4000 rpm. The KMPR 1050 curve is the filled-square series and the topmost (thickest-film) curve at every rpm, consistent with its legend position (listed first) and Table 1's viscosity ordering (1050 = 13,000 cSt, the highest of the four, so it coats thickest at a given speed). A figure read, not a numeric table — no per-rpm table for this grade is published.

KMPR 1050 (23°C Japan & Asia): read from Figure 2 "Spin speed vs. Thickness for KMPR® 1000 resists (23°C Japan & Asia)", p.2 of the Kayaku Microchem/MicroChem "KMPR 1000 Chemically Amplified Negative Photoresist" datasheet (Ver. 4.2, UPenn nanoSOP mirror). The chart plots four curves (KMPR 1050/filled square, 1025/filled diamond, 1010/filled circle, 1005/open square), each with 4 markers at 1000/2000/3000/4000 rpm. KMPR 1050 is the filled-square series and the topmost (thickest-film) curve at every rpm, consistent with its legend position (listed first) and Table 1's viscosity ordering (1050 = 13,000 cSt, the highest of the four). A figure read — no numeric table of these values is published.

2 series redrawn from the manufacturer's published data — hover to read between points, click to pin.
  • Recommended program: dispense 1 ml of resist per inch (25 mm) of substrate diameter
  • spin at 500 rpm for 5-10 s at 100 rpm/s acceleration, then spin at the target speed for 30 s at 300 rpm/s acceleration.
  • The document publishes TWO spin curves for the same four resists at two different ambient conditions: Figure 1 (21°C, US & EU) and Figure 2 (23°C, Japan & Asia) — the curves are not identical (e.g. KMPR 1050 at 1000 rpm reads ~101 µm in Figure 1 vs. ~115 µm in Figure 2), a reminder that spin results are sensitive to coat-bowl ambient temperature/humidity and should be recharacterized on-tool.
  • Both curves are plotted above: Figure 1 (21°C US & EU) as the primary curve and Figure 2 (23°C Japan & Asia) as a second series.

SOURCE: "Coat" / "Recommended Program", p.1, and Figures 1-2, p.2.

Adhesion
HMDS not required — "Adhesion promoters are typically not required." HMDS pretreatment (MCC Primer 80/20) is recommended "for applications that require electroplating" — and the document's own Plating process recipe lists HMDS as its first step.1
02 / Bake

Soft bake

Soft bake
100 °C · hotplate
Notes
Recommended bake temperature is 100°C (95-105°C also usable, per text) — this scalar temperature is explicit in the document. Time is published as a THICKNESS-BINNED table only up to 80 µm: 5-11 µm → 5 min; 12-20 µm → 7 min; 21-30 µm → 12 min; 31-55 µm → 15 min; 56-80 µm → 20 min. KMPR 1050's own spin curve (Figure 1) reaches 101 µm at 1000 rpm, i.e. above the table's published range — the datasheet does not give a soft-bake time for film thicker than 80 µm at all, so no time is assumed for the thick end of this grade's range. Convection ovens are explicitly not recommended. A cool-down/re-heat 'wrinkle' check is described to confirm the film is fully dry.

SOURCE: Table 2 "Soft Bake Times" and "Soft Bake" section text, p.2

03 / Exposure

Exposure dose

KMPR 1050's dose is published against film thickness, not as a single number. Read the row for the film you coat and run a dose array around it.

As published
Dose climbs hard with thickness — 235–335 mJ/cm² at 5–11 µm, 1070–1465 mJ/cm² at 56–80 µm — and then the table stops at 80 µm, while this grade coats up to 101 µm at 1000 rpm.
Post-exposure bake
100 °C
KMPR 1050 — dose by film thickness
Film thicknessDose
5–11 µm235–335 mJ/cm²
12–20 µm355–485 mJ/cm²
21–30 µm500–645 mJ/cm²
31–55 µm665–1055 mJ/cm²
56–80 µm1070–1465 mJ/cm²
SOURCE: Microchem/MicroChem KMPR 1000 datasheet

Table 3 'Exposure Dose' of the Kayaku Microchem/MicroChem KMPR 1000 datasheet (Ver. 4.2). The published table stops at 80 µm — no dose is given above that, which is inside KMPR 1050's own coating range. Not attributed to a specific wavelength.

04 / Development

Development

Developer
2.38% TMAH (0.26N) aqueous alkaline developer (primary); SU-8 Developer (solvent-based) is also usable as an alternative
Dilution
2.38% TMAH (0.26N), used at this standard concentration (not diluted from a stock in the document)
Time
Not published — characterize on-tool
Method
immersion
Rinse
DI water, ~20 s spray rinse, then filtered air/N2 dry (TMAH path). If the optional SU-8-developer alternative is used instead, rinse is ~10 s fresh developer spray then ~10 s IPA spray, per the SU-8-developer note.
Developer family
TMAH or solvent

SOURCE: "Develop" and "Rinse and Dry" sections plus Table 5 (TMAH) and Table 6 (SU-8 developer), p.3

05 / Post-processing

Hard bake, etch & strip

Etch resistance
Listed as a Feature: "Excellent dry etch resistance." Demonstrated in an application photo ("Etched Trenches", 10 µm features, 65 µm deep, credited to ULVAC) consistent with use as a DRIE (deep reactive ion etch) mask. No quantitative etch rate or selectivity numbers are published.2
Stripper
MicroChem Remover PG (NMP): heat bath to 80°C, immerse substrate 10-20 minutes (actual time depends on resist thickness and agitation, e.g. ultrasound). For fully electroformed metal structures, a stronger sequence is given: Remover PG 10 min @80°C → DIW rinse → XP Remover K (epoxy stripping chemistry) 10 min @80°C → DIW rinse → XP Neutralizer K 3 min @25°C. Plasma removal: RIE 200 W, 80 sccm O2, 8 sccm CF4, 100 mTorr, 10°C.3
Storage
Store frozen, in tightly closed, upright containers, at 14°F (-10°C), away from light, heat, acids, and ignition sources. Shelf life is twelve months at 14°F (-10°C), but typically only one to two months at room temperature. Defrost at room temperature for 24 hours before use.4

Not published for this resist: Hard bake, Descum — characterize on-tool.

SOURCE: "Plating" section note, p.3

06 / Applications

Where it's used

Practical notes from the datasheet

KMPR 1050 is the thickest-coating grade in Kayaku Microchem/MicroChem's KMPR 1000 line and, unlike the solvent-developed SU-8 2000 family, is a chemically amplified epoxy resist designed to develop in aqueous TMAH — a meaningful process difference worth flagging for anyone assuming all thick epoxy negative resists behave like SU-8. Its published process tables (soft bake, exposure dose, TMAH develop time) only cover film thicknesses up to 80 µm, while KMPR 1050's own spin curve reaches roughly 101 µm at 1000 rpm; process engineers working at the thick end of this grade's range will need to extrapolate or characterize on-tool, since the datasheet simply does not publish numbers there. PEB time follows a thickness-threshold rule (2/3/4 minutes at 25/50 µm cutoffs) rather than a continuous table. A distinctive storage gotcha: KMPR 1000 resists must be stored frozen (14°F/-10°C) and require a full 24-hour room-temperature thaw before use — treating it like a room-temperature-stable resist will produce inconsistent films. The resist strips cleanly with Remover PG when only lightly cross-linked, but a fully electroformed/plated structure needs the stronger Remover PG → XP Remover K → XP Neutralizer K sequence to fully dissolve.

07 / Family

Grades in this family

Other grades in the KMPR 1000 series line differ mainly in coating thickness:

KMPR 1000 series — grade comparison
GradeThickness
KMPR 10055.1–9.7 µm
KMPR 1050 (this page)34–115 µm
08 / Troubleshooting

Troubleshooting

Common failure modes for KMPR 1050, answered from the manufacturer's datasheet and application notes. These are starting points — your substrate, tooling and environment shift the specifics, so calibrate on-tool.

Why don't the KMPR 1050 process tables cover my film thickness?

KMPR 1050 coats to roughly 101 µm at 1000 rpm (115 µm on the 23°C curve), but the datasheet's soft-bake, exposure-dose and TMAH-develop tables stop at 80 µm. Above that there simply are no published numbers, so at the thick end of this grade you must extrapolate the trend and characterize on-tool rather than read a value off the sheet.

SOURCE: Kayaku Microchem KMPR 1000 datasheet (Ver. 4.2) — Tables 2, 3 and 5, p.2–3

What post-exposure bake does KMPR 1050 need?

PEB is at 100°C (95–105°C usable) on a hotplate, with time set by a thickness-threshold rule rather than a table: 2 min at ≤25 µm, 3 min above 25 µm and 4 min above 50 µm. KMPR 1050's 44–101 µm range straddles both thresholds, so choose by your actual film. A latent mask image should already be visible after about 1 min of PEB; if none appears, exposure or heat was insufficient.

SOURCE: Kayaku Microchem KMPR 1000 datasheet (Ver. 4.2) — Post Exposure Bake (PEB), p.3

Why is my KMPR 1050 film wrinkling or not fully drying on soft bake?

Soft bake at 100°C on a level hotplate — convection ovens are explicitly not recommended, since a skin can trap solvent. Published times are thickness-binned up to 80 µm (e.g. 15 min for 31–55 µm, 20 min for 56–80 µm). Use the datasheet's cool-down/re-heat 'wrinkle' check to confirm the film is fully dry before exposure.

SOURCE: Kayaku Microchem KMPR 1000 datasheet (Ver. 4.2) — Table 2 Soft Bake Times and Soft Bake section, p.2

Does KMPR 1050 need an adhesion promoter?

Adhesion promoters are typically not required. The exception is electroplating: HMDS pretreatment (MCC Primer 80/20) is recommended for plating applications, and the datasheet's own plating recipe lists HMDS as its first step. Note plated structures also change how the resist strips — a fully electroformed part needs the Remover PG → XP Remover K → XP Neutralizer K sequence.

SOURCE: Kayaku Microchem KMPR 1000 datasheet (Ver. 4.2) — Substrate Preparation and Plating, p.1 & p.3

09 / Sources

Sources & disclaimer

Cited above
  1. "Substrate Preparation", p.1, and "Plating", p.3.
  2. "Features" list and application photos, p.1.
  3. "Removal" / "Process Recommendation" / "Plasma Removal", p.3.
  4. "Storage", p.4.
Research using this resist
  1. Lee et al.. Fabrication of thick electroforming micro mould using a KMPR negative tone photoresist. Journal of Micromechanics and Microengineering (2008). doi:10.1088/0960-1317/18/5/055032
    180 µm, 18:1 KMPR molds — strippable, unlike SU-8.
  2. Shin et al.. UV Lithography and Molding Fabrication of Ultrathick Micrometallic Structures Using a KMPR Photoresist. Journal of Microelectromechanical Systems (2010). doi:10.1109/JMEMS.2010.2045880
    KMPR molds for mm-wave traveling-wave-tube structures.

Manufacturer datasheet values are starting points; optimal parameters depend on your substrate, equipment and environment. Product names and trademarks belong to their respective owners. NANYTE is not affiliated with the manufacturers listed. Last updated 2026-07-26.

Cite this recipe

NANYTE. "KMPR 1050 process recipe." NANYTE Photoresist Library. https://nanyte.com/photoresists/kmpr-1050. Accessed 2026-07-26.

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