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KMPR 1035 process recipe

KMPR 1035 is the thickest KMPR viscosity, coating 28-115 µm in a single step — and most of its upper range sits beyond where the datasheet's process tables stop.

https://nanyte.com/photoresists/kmpr-1035 · last updated 2026-09-12

At a glance
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Manufacturer
Kayaku Advanced Materials
Tone
negative
Chemistry
Epoxy (SU-8 type)
Thickness
28–115 µm
Developer
2.38 % TMAH (0.26 N) aqueous alkaline developer; SU-8 developer (solvent) may be used instead
Applications
High aspect ratio · MEMS structural · Electroplating / molding · Etch mask

Cross-checked — two independent extractions agree on the spin curve and the single-value figures.

The exposed resist stays after development; the unexposed film dissolves. Schematic cross-sections for KMPR 1035 — feature width, film aspect ratio and sidewall angle are illustrative, not to scale.
01 / Coating

Spin coating

Spin curve for KMPR 1035: film thickness in µm against spin speed in rpm.0501001501k2k3k4kSPIN SPEED (rpm)THICKNESS (µm)
Data points
KMPR 1035 — film thickness (µm) by spin speed (rpm)
SeriesrpmµmPublished dose
KMPR 10351000115
200056
300037
665–1055 mJ/cm² · 31–55 µm row
400028
500–645 mJ/cm² · 21–30 µm row
within 10 % of a bracket edge

Values are the manufacturer’s starting points, not a guarantee — characterize on your own tool. Series digitized from a published figure are approximate (±10 %).

Published dose is the datasheet’s own thickness bracket, quoted as printed — the full table and its citation are in the exposure section. A thickness the table does not cover shows nothing, and a thickness within 10 % of a bracket edge shows every bracket it could fall in.

read from figure — the filled-square trace legended KMPR 1035 on Figure 1, 'KMPR 1000 Thickness vs. Spin Speed', p.2, the highest of the five traces. Four plotted markers; no numeric table accompanies the chart.

Redrawn from the manufacturer's published data — hover to read between points, click to pin.
  • The steepest trace on the chart by a wide margin: 115 µm at 1000 rpm less than halves to 55.5 µm at 2000, then falls to 36.5 and 28 µm.
  • Thickness is therefore extremely sensitive to speed at the slow end, and the 1000 rpm point also sits above the 110 µm the datasheet quotes as the series maximum — treat anything past about 80 µm as a target to establish on a test wafer, not to read off a curve.
  • Table 1 puts this grade at 65 % solids and 8400 cSt, the most viscous in the line.
  • The recommended program is a 500 rpm / 5-10 s spread at 100 rpm/s acceleration, then 30 s at the final speed at 300 rpm/s, dispensing 1 ml of resist per inch of substrate diameter.
Adhesion
HMDS recommended — Adhesion promoters are described as typically unnecessary; substrates should be clean and dry, ideally after a piranha clean and a de-ionized water rinse, or an O2 RIE/barrel-asher clean. HMDS priming is recommended specifically where the film will be used for electroplating.
02 / Bake

Soft bake

Soft bake
100 °C (95–105 °C) · hotplate
Notes
100 °C on a level hotplate, with 95-105 °C also usable. Convection ovens are advised against — a skin forms and traps solvent, which on the thickest film in the line is the failure this warning is really about. Time is thickness-binned: 12 min for 21-30 µm, 15 min for 31-55 µm and 20 min for 56-80 µm. Above 80 µm the table stops, so most of this grade's upper range has no published bake time at all. Bake, cool to room temperature, then return the wafer to the hotplate — visible wrinkling means it needs longer, and here that check matters more than anywhere else in the series.

SOURCE: Soft Bake section and Table 2, p.2 of the KMPR 1000 datasheet (Ver. 6, December 2019)

03 / Exposure

Exposure dose

KMPR 1035's dose is published against film thickness, not as a single number. Read the row for the film you coat and run a dose array around it.

As published
Dose follows the coating rather than the grade: 500-645 mJ/cm² at 21-30 µm rising to 1070-1465 mJ/cm² at 56-80 µm, with nothing published above 80 µm — which on this grade means no published dose for anything coated slower than roughly 1500 rpm. Reflective substrates cost more again, at 1.5× on glass, Pyrex and ITO and 1.5-2× on gold, aluminium, copper, nickel and titanium against 1× on silicon.
Post-exposure bake
100 °C (95–105 °C) · hotplate
KMPR 1035 — dose by film thickness
Film thicknessDose
21–30 µm500–645 mJ/cm²
31–55 µm665–1055 mJ/cm²
56–80 µm1070–1465 mJ/cm²
SOURCE: KMPR 1000 datasheet

Table 3 'Exposure Dose' of the KMPR 1000 datasheet (Ver. 6). The three bins carried here are the ones this grade's thickness range crosses; the table's top bin ends at 80 µm, well below the 115 µm this grade reaches at 1000 rpm. The table is not attributed to a specific wavelength.

04 / Development

Development

Developer
2.38 % TMAH (0.26 N) aqueous alkaline developer; SU-8 developer (solvent) may be used instead
Method
immersion, spray or spray-puddle
Rinse
After TMAH, spray rinse with de-ionized water for 20 s and blow dry with filtered air or nitrogen. After SU-8 developer, spray with fresh developer for about 10 s, then isopropyl alcohol for another 10 s, then blow dry — a white film during the IPA rinse means the film is under-developed and needs more developer.
Developer family
TMAH or solvent

Not published for this resist: Dilution, Time — characterize on-tool.

SOURCE: Development and Rinse and Dry sections with Tables 6 and 7, p.3-4 of the KMPR 1000 datasheet (Ver. 6, December 2019)

05 / Post-processing

Hard bake, etch & strip

Hard bake
Not published — characterize on-tool
Descum
RIE, 2 min at 100 W with 10 sccm O2 at 100 mTorr — quoted as step 3 of the datasheet's plating sequence.
Etch resistance
"Excellent dry etch resistance" (Features, p.1); the series is positioned for DRIE work, and the datasheet's own example shows 10 µm features etched to 65 µm deep.
Stripper
Remover PG (NMP) at 80 °C for 10-20 min by immersion, provided the film was never hard baked — on the thickest grade in the line expect the long end and use ultrasound. Plasma removal where needed: RIE at 200 W with 80 sccm O2 and 8 sccm CF4, 100 mTorr, 10 °C.
Storage
Store frozen at -10 °C (14 °F) in tightly closed upright containers, away from light, heat, acids and ignition sources. Shelf life is thirteen months frozen, typically one to two months at room temperature. Defrost at room temperature for 24 h before use.
06 / Applications

Where it's used

Practical notes from the datasheet

KMPR 1035 is the thickest and most viscous grade in Kayaku's chemically amplified epoxy negative line, reaching over 100 µm in a single coat — the regime of tall copper pillars and deep DRIE masks. It replaced KMPR 1050 in the current revision of the datasheet, which is the first thing to check if you are working from an older process: 1050 no longer appears, and 1035 is thinner at the same spin speed. The honest caution on this grade is where the published process runs out. Its curve reaches 115 µm at 1000 rpm, but the soft-bake, exposure and develop tables all stop at 80 µm, so above that there is no published bake time, no clearing dose and no develop time — only the post-exposure bake table, whose top row is open-ended, still applies. In practice that means the curve crosses 80 µm at roughly 1500 rpm, so anything coated slower than that has to be characterised on-tool. Below 80 µm the rest of the series discipline holds: the post-exposure bake is where cross-linking happens and is not optional, reflective substrates need 1.5-2× the dose, and hard baking is discouraged because an un-hard-baked film is the one that strips in Remover PG.

07 / Family

Grades in this family

Other grades in the KMPR 1000 series line differ mainly in coating thickness:

KMPR 1000 series — grade comparison
GradeThickness
KMPR 10054.5–9.5 µm
KMPR 101010–27 µm
KMPR 101512.5–40 µm
KMPR 102521.5–87 µm
KMPR 1035 (this page)28–115 µm
KMPR 105034–115 µm
08 / Sources

Sources & disclaimer

Manufacturer datasheet values are starting points; optimal parameters depend on your substrate, equipment and environment. Product names and trademarks belong to their respective owners. NANYTE is not affiliated with the manufacturers listed. Last updated 2026-09-12.

Cite this recipe

NANYTE. "KMPR 1035 process recipe." NANYTE Photoresist Library. https://nanyte.com/photoresists/kmpr-1035. Accessed 2026-09-12.

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