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LOR 7B process recipe

LOR 7B is the thinnest of the fast-dissolving B underlayers, coating 0.32-0.90 µm, for lift-off where a wide undercut is wanted but the sacrificial film has to stay under a micron.

https://nanyte.com/photoresists/lor-7b · last updated 2026-09-12

At a glance
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Manufacturer
MicroChem (MCC) — now Kayaku Advanced Materials
Tone
Not photoimageable (underlayer)
Chemistry
Ancillary (not photoimageable)
Thickness
0.3–0.9 µm
Exposure dose
Not exposed — dissolves in developer
Developer
No specific commercial developer product is named for this grade; the datasheet states LOR/PMGI is compatible with both metal-ion-free (TMAH) and metal-ion-bearing developer chemistries.
Applications
Lift-off

Cross-checked — two independent extractions agree on the spin curve and the single-value figures.

The underlayer is never exposed: it sits beneath an imaged top resist and the developer undercuts it laterally, leaving the overhang lift-off relies on. Schematic cross-sections for LOR 7B — feature width, film aspect ratio and sidewall angle are illustrative, not to scale.
01 / Coating

Spin coating

Spin curve for LOR 7B: film thickness in µm against spin speed in rpm.0.20.40.60.81.01k2k3k4kSPIN SPEED (rpm)THICKNESS (µm)
Data points
LOR 7B — film thickness (µm) by spin speed (rpm)
Seriesrpmµm
LOR 7B10000.90
15000.72
20000.57
25000.44
30000.39
35000.34
40000.32

Values are the manufacturer’s starting points, not a guarantee — characterize on your own tool. Series digitized from a published figure are approximate (±10 %).

read from figure — the dark-blue filled-circle trace legended LOR 7B on the 'Thickness vs. Spin Speed - LOR B Thick Series' chart, p.5. Seven plotted markers at 500 rpm intervals; no numeric table accompanies the chart.

Redrawn from the manufacturer's published data — hover to read between points, click to pin.
  • The lowest trace on the B-series chart, falling from 9,000 Å at 1000 rpm to 3,200 Å at 4000 rpm — a factor of nearly three, so speed is a real lever across this grade's whole range, unlike the thicker B grades whose curves flatten early.
  • Most of that fall happens below 2500 rpm.
  • Coating parameters are published for the product line rather than per grade: 5 ml dispensed dynamically over 3-5 s onto a 150 mm wafer at 300-500 rpm, 10,000 rpm/s acceleration to a 3,000 rpm terminal speed, 45 s spin, with EBR PG for edge-bead and whisker removal.
  • A substrate of irregular shape needs a slower spin for an even coat.
Adhesion
HMDS not required — "Primers, such as HMDS, are typically not required" when LOR/PMGI is used as recommended; the datasheet describes excellent adhesion across semiconductor substrates. To dehydrate the surface first, bake at 200 °C for 5 min. LOR/PMGI is virtually insoluble in typical photoresist solvents, so a properly baked underlayer does not intermix with the imaging resist above it.
02 / Bake

Soft bake

Soft bake
Not published — characterize on-tool
Notes
The prebake does two jobs — it dries the film and it fixes the dissolution and undercut rate — and no grade-specific temperature or time is published. The recommended prebake range for the product line is 160-210 °C, hotplate preferred, and some PMGI products bake as high as 280 °C. Prebake temperature has the greatest influence on undercut rate, with prebake time, developer choice, develop mode and especially develop time behind it. Hotter and longer both slow the dissolution and tighten the undercut. On a B-series film that lever matters more than on an A grade, because the starting dissolution rate is already high; the published undercut-versus-bake curves (Figures 5a and 5b) are measured on LOR 10B, the nearest B sibling to this grade.
SOURCE: "Soft-Bake/Prebake Process" section and Figures 5a-5b, Kayaku…

"Soft-Bake/Prebake Process" section and Figures 5a-5b, Kayaku "LOR and PMGI Resists" technical data sheet, Rev. D (August 2023)

03 / Exposure

Exposure

LOR 7B is not photoimageable. It is not exposed at all — it is coated beneath an imaged top resist and undercut laterally during development. See the development step below.

04 / Development

Development

Developer
No specific commercial developer product is named for this grade; the datasheet states LOR/PMGI is compatible with both metal-ion-free (TMAH) and metal-ion-bearing developer chemistries.
Developer family
TMAH or buffered alkaline

Not published for this resist: Dilution, Time, Method, Rinse — characterize on-tool.

SOURCE: Product description, the LOR/PMGI process-flow section and the…

Product description, the LOR/PMGI process-flow section and the product selection guide, Kayaku "LOR and PMGI Resists" technical data sheet, Rev. D (August 2023)

05 / Post-processing

Hard bake, etch & strip

Stripper
Remover PG. EBR PG removes edge beads and whiskers and is also an effective spin-bowl cleaner and a rework solvent for unbaked wafers.
Storage
Store upright in original sealed containers in a dry area between 4 and 27 °C (40-80 °F), away from ignition sources, light, heat, oxidants, acids and reducers. Do not use after the expiration date.

Not published for this resist: Hard bake, Descum, Etch resistance — characterize on-tool.

06 / Applications

Where it's used

Practical notes from the datasheet

LOR 7B is a PMGI-based sacrificial underlayer from the fast-dissolving B series, spun beneath a conventional photoresist and never exposed itself. The A, B and C series are the same polymer family tuned to different dissolution rates: a B grade opens its undercut faster than an A grade for the same prebake and develop. That is what you want when the deposited film is thick enough to need a generous ledge to break at, and what you do not want when the feature is fine and the undercut would run under it. What makes this grade the useful end of the B line is that it stays sub-micron — 0.32 to 0.90 µm — so you get B-series speed at a thickness the 10B, 15B, 20B and 30B grades would overshoot. Everything that sets the final ledge is a process variable rather than a product property: prebake temperature first, then develop time, then the developer and develop mode. Nothing here is exposed, so there is no dose, no tone and no post-exposure bake.

07 / Family

Grades in this family

Other grades in the LOR B series line differ mainly in coating thickness:

LOR B series — grade comparison
GradeThickness
LOR 7B (this page)0.3–0.9 µm
LOR 10B0.7–1.6 µm
LOR 15B1–2.2 µm
LOR 20B1.3–3.5 µm
LOR 30B1.6–4.3 µm
08 / Sources

Sources & disclaimer

Manufacturer datasheet values are starting points; optimal parameters depend on your substrate, equipment and environment. Product names and trademarks belong to their respective owners. NANYTE is not affiliated with the manufacturers listed. Last updated 2026-09-12.

Cite this recipe

NANYTE. "LOR 7B process recipe." NANYTE Photoresist Library. https://nanyte.com/photoresists/lor-7b. Accessed 2026-09-12.

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