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LOR 20B process recipe

LOR 20B coats 1.30-3.45 µm, a sacrificial thickness chosen when the metal being lifted off is thick enough that a one-micron underlayer would not break cleanly at the edge.

https://nanyte.com/photoresists/lor-20b · last updated 2026-09-12

At a glance
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Manufacturer
MicroChem (MCC) — now Kayaku Advanced Materials
Tone
Not photoimageable (underlayer)
Chemistry
Ancillary (not photoimageable)
Thickness
1.3–3.5 µm
Exposure dose
Not exposed — dissolves in developer
Developer
No specific commercial developer product is named for this grade; the datasheet states LOR/PMGI is compatible with both metal-ion-free (TMAH) and metal-ion-bearing developer chemistries.
Applications
Lift-off

Cross-checked — two independent extractions agree on the spin curve and the single-value figures.

The underlayer is never exposed: it sits beneath an imaged top resist and the developer undercuts it laterally, leaving the overhang lift-off relies on. Schematic cross-sections for LOR 20B — feature width, film aspect ratio and sidewall angle are illustrative, not to scale.
01 / Coating

Spin coating

Spin curve for LOR 20B: film thickness in µm against spin speed in rpm.1.01.52.02.53.03.54.01k2k3k4kSPIN SPEED (rpm)THICKNESS (µm)
Data points
LOR 20B — film thickness (µm) by spin speed (rpm)
Seriesrpmµm
LOR 20B10003.5
15002.6
20002.0
25001.7
30001.4
35001.4
40001.3

Values are the manufacturer’s starting points, not a guarantee — characterize on your own tool. Series digitized from a published figure are approximate (±10 %).

read from figure — the green filled-triangle trace legended LOR 20B on the 'Thickness vs. Spin Speed - LOR B Thick Series' chart, p.5. Seven plotted markers at 500 rpm intervals; no numeric table accompanies the chart.

Redrawn from the manufacturer's published data — hover to read between points, click to pin.
  • Most of the thickness swing happens in the first half of the sweep: 34,500 Å at 1000 rpm falls to 20,500 Å by 2000 rpm, then only to 13,000 Å by 4000 rpm.
  • So a target near the thick end sits where the curve is steepest and thickness is most sensitive to speed and to dispense — worth confirming on a test wafer rather than reading off the chart.
  • Coating parameters are published for the product line rather than per grade: 5 ml dispensed dynamically over 3-5 s onto a 150 mm wafer at 300-500 rpm, 10,000 rpm/s acceleration to a 3,000 rpm terminal speed, 45 s spin, with EBR PG for edge-bead and whisker removal.
  • An irregularly shaped substrate needs a slower spin.
Adhesion
HMDS not required — "Primers, such as HMDS, are typically not required" when LOR/PMGI is used as recommended; the datasheet describes excellent adhesion across semiconductor substrates. To dehydrate the surface first, bake at 200 °C for 5 min. LOR/PMGI is virtually insoluble in typical photoresist solvents, so a properly baked underlayer does not intermix with the imaging resist above it.
02 / Bake

Soft bake

Soft bake
Not published — characterize on-tool
Notes
The prebake dries the film and fixes its dissolution and undercut rate, and no grade-specific temperature or time is published. The recommended prebake range for the product line is 160-210 °C, hotplate preferred, and some PMGI products bake as high as 280 °C. Prebake temperature has the greatest influence on undercut rate, with prebake time, developer choice, develop mode and especially develop time behind it. At this thickness the bake also has several times more solvent to drive out than a sub-micron coat, so the time half of that matrix is worth exploring on a test wafer; the published undercut-versus-bake curves (Figures 5a and 5b) are measured on LOR 10B, a film roughly half this thickness.
SOURCE: "Soft-Bake/Prebake Process" section and Figures 5a-5b, Kayaku…

"Soft-Bake/Prebake Process" section and Figures 5a-5b, Kayaku "LOR and PMGI Resists" technical data sheet, Rev. D (August 2023)

03 / Exposure

Exposure

LOR 20B is not photoimageable. It is not exposed at all — it is coated beneath an imaged top resist and undercut laterally during development. See the development step below.

04 / Development

Development

Developer
No specific commercial developer product is named for this grade; the datasheet states LOR/PMGI is compatible with both metal-ion-free (TMAH) and metal-ion-bearing developer chemistries.
Developer family
TMAH or buffered alkaline

Not published for this resist: Dilution, Time, Method, Rinse — characterize on-tool.

SOURCE: Product description, the LOR/PMGI process-flow section and the…

Product description, the LOR/PMGI process-flow section and the product selection guide, Kayaku "LOR and PMGI Resists" technical data sheet, Rev. D (August 2023)

05 / Post-processing

Hard bake, etch & strip

Stripper
Remover PG — expect the long end of any strip time at this thickness. EBR PG removes edge beads and whiskers and is also an effective spin-bowl cleaner and a rework solvent for unbaked wafers.
Storage
Store upright in original sealed containers in a dry area between 4 and 27 °C (40-80 °F), away from ignition sources, light, heat, oxidants, acids and reducers. Do not use after the expiration date.

Not published for this resist: Hard bake, Descum, Etch resistance — characterize on-tool.

06 / Applications

Where it's used

Practical notes from the datasheet

LOR 20B is a thick PMGI-based sacrificial underlayer from the fast-dissolving B series, spun beneath a conventional photoresist and never exposed. Underlayer thickness is chosen against the deposited film, not against the feature: the sacrificial layer has to be thick enough that the metal landing on the substrate and the metal landing on top of the imaging resist are genuinely disconnected, or the lift-off tears instead of releasing. At 1.30-3.45 µm this grade is aimed at depositions the sub-micron grades cannot break. The trade is that a thick, fast-dissolving film keeps undercutting for as long as the imaging resist above it is developing, so the ledge can travel further than intended under fine features — which is why the datasheet's own thick-film example pairs a 30-series underlayer with 20 µm lines rather than sub-micron ones. Prebake temperature remains the primary control, with develop time close behind.

07 / Family

Grades in this family

Other grades in the LOR B series line differ mainly in coating thickness:

LOR B series — grade comparison
GradeThickness
LOR 7B0.3–0.9 µm
LOR 10B0.7–1.6 µm
LOR 15B1–2.2 µm
LOR 20B (this page)1.3–3.5 µm
LOR 30B1.6–4.3 µm
08 / Sources

Sources & disclaimer

Manufacturer datasheet values are starting points; optimal parameters depend on your substrate, equipment and environment. Product names and trademarks belong to their respective owners. NANYTE is not affiliated with the manufacturers listed. Last updated 2026-09-12.

Cite this recipe

NANYTE. "LOR 20B process recipe." NANYTE Photoresist Library. https://nanyte.com/photoresists/lor-20b. Accessed 2026-09-12.

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