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WBR 2000 process recipe

WBR 2000 is DuPont's thick negative dry film for wafer bumping and copper-pillar plating, supplied as 50, 75, 100 and 120 µm laminated sheets. It takes 220-520 mJ/cm² depending on the sheet, develops in a carbonate spray in roughly 1.7 to 6 min total, and is positioned for in-via and mushroom plating, with a note that high-temperature paste reflow needs more dose.

https://nanyte.com/photoresists/dupont-wbr2000 · last updated 2026-10-15

At a glance
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Manufacturer
DuPont
Tone
negative
Thickness
50–120 µm
Developer
Na2CO3 or K2CO3, 0.6-1.2 wt% (1.0 wt% preferred)
Applications
Electroplating / molding

Cross-checked — the spin curve (where published) and the single-value figures were read twice, independently, from the datasheet, with any disagreement settled against it.

The exposed resist stays after development; the unexposed film dissolves. Schematic cross-sections for WBR 2000 — feature width, film aspect ratio and sidewall angle are illustrative, not to scale.
—01 / Coating

Coating — dry-film lamination

WBR 2000 is supplied as a pre-cut dry-film sheet and applied by hot-roll lamination — it is not spin-coated. Thickness is fixed per sheet, 50–120 µm, selected by sheet rather than by spin speed.

  • WBR is hot-roll laminated, not spin-coated, so thickness is fixed by the sheet.
  • Hot roll laminator conditions: roll 85-110 °C (95 °C preferred), speed 0.6-1.5 m/min (1.2 m/min preferred), pressure 15-40 psig
  • for an automatic laminator the sheet refers you to the equipment maker and DuPont.
  • If the film wrinkles, reduce roll pressure and/or temperature, particularly if the laminator is not well aligned.
  • Let wafers cool to room temperature before exposure and before further processing, and never stack substrates horizontally, which imprints random defects.
  • Expose within 3 days of lamination.
  • The polyester cover sheet stays on for exposure and must be removed before development.
Adhesion
No adhesion promoter is named. The surface must be free of organic contamination and metal oxides; where possible clean with a light 2-3 % sulfuric acid solution, rinse in DI water and dry with nitrogen, immediately before lamination. Listed compatible surfaces are silicon, silicon nitride, sputtered copper, sputtered gold and PI/BCB with UBM. An optional post-lamination bake is offered for extra-smooth surfaces and aggressive applications.
—02 / Bake

Soft bake

Soft bake
Not published — characterize on-tool
Notes
No soft bake. The only bake before exposure is the optional post-lamination bake to promote adhesion: oven 55-75 °C (65 °C preferred) for 15-20 min (20 min preferred). The sheet gives no hotplate option for this step and notes that the temperature varies with film thickness, substrate and process.

SOURCE: Part 4 'Post-Lamination Bake (Optional)', p.2 of the DuPont WBR 2000 Series data sheet

—03 / Exposure

Exposure dose

WBR 2000's dose is published per sheet thickness, not as a single number. Read the row for the sheet you laminate and run a dose array around it.

As published
Dose follows the sheet: 220-460 mJ/cm² for the 50 µm film, 250-500 for 100 µm and 260-520 for 120 µm, with the high end for aggressive plating and for high-temperature reflow.
WBR 2000 — dose per sheet thickness
SheetDose
50 µm220–460 mJ/cm²
75 µm240–480 mJ/cm²
100 µm250–500 mJ/cm²
120 µm260–520 mJ/cm²
SOURCE: 'Recommended Exposure Range' table (mJ/cm2), Part 5, p.2 of…

'Recommended Exposure Range' table (mJ/cm2), Part 5, p.2 of the DuPont WBR 2000 Series data sheet: WBR2050 220-460, WBR2075 240-480, WBR2100 250-500, WBR2120 260-520. The table carries no wavelength label; the text says the film has peak absorption at 365 nm and i-line lamps are highly recommended, and that all energies were measured at the film surface with an IL-1400A radiometer and SSD001A probe (275-400 nm sensitivity), p.3.

—04 / Development

Development

Developer
Na2CO3 or K2CO3, 0.6-1.2 wt% (1.0 wt% preferred)
Method
spray (conditions given for developers with non-stationary spray nozzles)
Rinse
Remove the polyester cover sheet before developing. Rinse right after development with hard water (150-300 ppm CaCO3 equivalent, hardened with magnesium sulfate if needed) at 21-25 °C and 1.4-2.4 bar, with the develop-to-rinse dwell ratio at least 2:1; then spin dry at 2500-3500 rpm (3000 rpm preferred) for 20-40 s with nitrogen. Keep white-light exposure to a minimum while wafers wait after development.
Developer family
Buffered alkaline

Not published for this resist: Dilution, Time — characterize on-tool.

SOURCE: Part 7 'Development', Rinsing and Drying Recommendations, p.3 of the DuPont WBR 2000 Series data sheet

—05 / Post-processing

Hard bake, etch & strip

Descum
Plasma etching (ashing) is recommended to clear organic residue and improve wetting before electroplating. Reference parameters from the sheet: O2 at 250 sccm (printed as 'SCLL'), 250 W, 500 mTorr, 30 s dwell, offered for reference only.
Stripper
Stripper named as successfully used: EKC 108 (EKC Technology), at 50-85 °C (125-185 °F). The sheet says proprietary chemistries give faster removal and higher film loading and reduce attack on surface metallurgy. Total removal time depends on exposure dose, bake cycle and hold times.
Storage
Store at 5-21 °C (40-70 °F) and 40-60 % relative humidity. Protect the film through lamination and development from UV and visible light up to 450 nm using gold fluorescent safe lights; high-intensity yellow light (above 75 foot-candles) can change photospeed over time and should be avoided. No shelf life is printed.

Not published for this resist: Hard bake, Etch resistance — characterize on-tool.

SOURCE: Part 8 'Post-Development Bake (Optional)', pp.3-4 of the DuPont WBR 2000 Series data sheet

—06 / Applications

Where it's used

Practical notes from the datasheet

WBR 2000 is a 50-120 µm laminated film aimed at in-via and mushroom electroplating for wafer bumping and copper pillars; the sheet also lists photo-stencil use. The sheet lists plating in acid copper, tin/lead and tin, and says it is also compatible with nickel sulfamate, most lead-free electrolytes and acid gold baths under controlled conditions, with strong resistance to lifting and underplating (contact DuPont for details). Heat resistance is listed as a feature, and the exposure note says higher dose is required for high-temperature steps such as high-lead paste reflow. The develop table is split by wafer size and grade, and the 120 µm film on a 300 mm wafer takes up to 6 min in total. Allow no more than 3 days between lamination and exposure.

—07 / Troubleshooting

Troubleshooting

Common failure modes for WBR 2000, answered from the manufacturer's datasheet and application notes. These are starting points — your substrate, tooling and environment shift the specifics, so calibrate on-tool.

The film wrinkles during lamination. What does DuPont suggest?

Reduce the laminating roll pressure and/or temperature, especially if the laminator is not correctly aligned. The stated window is 85-110 °C and 15-40 psig at 0.6-1.5 m/min. Let wafers cool before the next step, and never stack substrates horizontally, which leaves random impression defects.

SOURCE: DuPont WBR 2000 Series data sheet DS06-118 Rev. 2.0 (08/07) - Part 2 'Lamination' notes, p.2

Why is the develop time so much longer for the 300 mm wafer?

The develop table is split by wafer size as well as by sheet. At 28 °C and 2 bar, the 120 µm sheet reaches clean in 144 s on a 200 mm wafer and 180 s on a 300 mm wafer, and the total develop time is 240-288 s against 280-360 s. For 200 mm and larger wafers the sheet suggests giving 30 % of the time to the wafer edges alone and 70 % to the whole surface, and adding 50-60 % beyond the clean point.

SOURCE: DuPont WBR 2000 Series data sheet DS06-118 Rev. 2.0 (08/07) -…

DuPont WBR 2000 Series data sheet DS06-118 Rev. 2.0 (08/07) - Part 7 'Development', Total Development Time table and notes, p.3

—08 / Sources

Sources & disclaimer

Manufacturer datasheet values are starting points; optimal parameters depend on your substrate, equipment and environment. Product names and trademarks belong to their respective owners. NANYTE is not affiliated with the manufacturers listed. Last updated 2026-10-15.

Cite this recipe

NANYTE. "WBR 2000 process recipe." NANYTE Photoresist Library. https://nanyte.com/photoresists/dupont-wbr2000. Accessed 2026-10-15.

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