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ma-N 1420 process recipe

ma-N 1420 is a negative-tone photoresist in micro resist technology's ma-N 1400 series, based on an aromatic bisazide/novolak chemistry with aqueous alkaline development. It is used both as a high dry/wet-etch-resistant mask for pattern transfer and, with a tunable vertical-to-undercut profile, as a single-layer lift-off resist for physical vapour deposition (evaporation/sputtering) of metals.

https://nanyte.com/photoresists/ma-n-1420 · last updated 2026-07-12

At a glance
Manufacturer
micro resist technology
Tone
negative
Chemistry
Bisazide-novolak
Thickness
1.4–3.4 µm
Exposure dose
550 mJ/cm²
Developer
ma-D 533/S
Applications
Etch mask · Lift-off
Etch maskSuitable forLift-offSuitable for

Cross-checked — two independent extractions agree.

01 / Coating

Spin coating

ma-N 1420 is spin-coated to 1.4–3.4 µm. The curve below is redrawn from the manufacturer's published data — read your target thickness off the vertical axis and take the matching spin speed as a starting point.

Spin curve for ma-N 1420: film thickness in µm against spin speed in rpm.0.001.02.03.04.01k2k3k4k5k6kSPIN SPEED (rpm)THICKNESS (µm)
Data points
ma-N 1420 — film thickness (µm) by spin speed (rpm)
Seriesrpmµm
ma-N 142010003.4
20002.4
30002.0
40001.7
50001.5
60001.4

Values are the manufacturer's starting points, not a guarantee; verify on your own tool. Characterize on-tool. Series digitized from a published figure were independently cross-checked by a second blind read; treat those values as approximate (±10 %).

re-extracted 2026-07-12, pixel-calibrated via PyMuPDF vector-path extraction (the chart is drawn as native PDF vector line segments, so the trace's true (x,y) coordinates were pulled directly from the page's vector drawing commands rather than estimated; axes calibrated from the tick-label text bounding boxes). Fig. 1 ('Spin curves of the ma-N 1400 series, 30 s spin time'), p.3 (numbered p.2 on the printed page) of micro resist technology's 'Processing guidelines — Negative Tone Photoresist Series ma-N 1400' datasheet (doc code ls.05.11.25.02). The curve is a continuous line with no point markers, so values are exact line-crossings read only at the labelled gridlines (every 1000 rpm from 1000 to 6000) — never interpolated between them or extrapolated past the line's plotted range. The 3000 rpm point (1.97 µm) is cross-confirmed by the numeric table on p.1 ('Physical properties of the resist solution': Film Thickness 2.0 ± 0.1 µm, footnoted 'spin coated at 3000 rpm for 30 s'). Supersedes the earlier eyeball read (which also guessed intermediate 1500/2500 rpm points not distinguishable on the chart).

Redrawn from the manufacturer's published data — hover to read values between points, click to pin.

Substrates should be free of impurities/moisture, baked at 200°C and cooled immediately before coating (or O2/ozone plasma cleaned); HMDS is advised for adhesion to Si/SiO2. No dispense-volume/acceleration/edge-bead protocol is published for ma-N 1400 (unlike some other resist datasheets); equipment used to generate the datasheet's own data: Convac or Suss RC5 spin coater without cover, 3000 rpm / 30 s reference condition.

Adhesion
HMDS recommended — HMDS recommended as an adhesion promoter for Si and SiO2 substrates. Substrates should be free of impurities and moisture, baked at 200°C and cooled to room temperature immediately before coating; oxygen or ozone plasma cleaning is an accepted alternative.
02 / Bake

Soft bake

Soft bake
100 °C · 2 min · hotplate
Notes
100°C / 120 s is the standard hotplate prebake for the 2.0 µm ma-N 1420 film (thinner grades in the same series use shorter times at the same 100°C: ma-N 1405/1407 = 60 s, ma-N 1410 = 90 s). Oven alternative: 100–105°C for 15–30 min. Prebake temperature may be raised (max 160°C) or time extended to further increase etch resistance/thermal stability, at the cost of a longer required develop time. Recommended prebake temperature varies by substrate: 100–120°C (Si), 120°C (Au), 120°C (Si3N4), 100°C (GaAsP/GaAs).

SOURCE: Processing conditions - STANDARD PROCESS table + 'Prebake' section, p.2 and p.3, micro resist technology ma-N 1400 datasheet ls.05.11.25.02

03 / Exposure

Exposure dose

The manufacturer publishes 550 mJ/cm² (Broadband exposure with the dose measured/specified at λ = 365 nm (i-line); footnote 1 of the Processing Conditions table explicitly states 'broadband exposure, intensity measured at λ=365 nm'.). Dose scales with film thickness and depends on your optics, so treat it as a starting point and run a dose array.

As published
Broadband exposure with the dose measured/specified at λ = 365 nm (i-line); footnote 1 of the Processing Conditions table explicitly states 'broadband exposure, intensity measured at λ=365 nm'.

Not published for this resist: Dose at 365 nm, Dose at 405 nm — characterize on-tool.

SOURCE: Processing conditions - STANDARD PROCESS table, p.2, micro resist technology ma-N 1400 datasheet ls.05.11.25.02

04 / Development

Development

Developer
ma-D 533/S
Dilution
ready-to-use (undiluted)
Time
60 s
Method
immersion
Rinse
DI water
Developer family
TMAH-based

SOURCE: Processing conditions - STANDARD PROCESS table, p.2, micro resist technology ma-N 1400 datasheet ls.05.11.25.02. Development time for ma-N 1420 is 60 ± 10 s; developer temperature should be 20–25°C.

05 / Post-processing

Hard bake, etch & strip

Hard bake
100 °C · 30 min
Descum
Not published — characterize on-tool
Etch resistance
High wet and dry etch resistance (a headline characteristic of the ma-N 1400 series). Can be further increased by raising prebake temperature (up to 160°C max) or prebake time, or by an optional post-develop hardbake (100°C, ~30 min); developing time increases correspondingly.
Stripper
mr-Rem 660 (solvent-based) or ma-R 404/S (strongly alkaline) ready-to-use removers recommended; acetone, N-methylpyrrolidone (NMP), or O2 plasma also give residue-free removal. For lift-off specifically after PVD: mr-Rem 660 or NMP at 40–60°C with ultrasonic assist (acetone with ultrasonics also recommended).
Storage
Store at 18–25°C; do not refrigerate. Store resist and unprocessed films under yellow light, bottle closed when not in use. Shelf life 6 months from date of manufacture under these conditions. Best patterning results at 20–25°C ambient and 40–46% RH.

SOURCE: 'Hardbake (optional)' section, p.4, micro resist technology ma-N 1400 datasheet ls.05.11.25.02

06 / Applications

Where it's used

Etch maskLift-off

ma-N 1420 gives a nominal 2.0 ± 0.1 µm film at the reference 3000 rpm / 30 s spin condition. Standard processing (100°C/120s prebake, 550 mJ/cm² dose, 60s develop) yields near-vertical sidewalls. Undercut (lift-off) profiles are produced primarily by INCREASING develop time (the manufacturer's preferred lever) and/or reducing exposure dose, while holding prebake conditions at standard values — the datasheet's own worked example (2.0 µm film, 100°C/120s prebake, 550 mJ/cm² dose) shows undercut of 0.6/0.8/1.7/2.1 µm for ma-D 533/S develop times of 65/80/100/120 s respectively. Raising prebake temperature (up to 160°C) and/or extending prebake time reduces undercut for a given develop time and improves thermal stability for sputtering, but increases the develop time needed. For clean PVD lift-off, resist thickness should be 1.5–2× the metal deposition thickness. Exposure dose must be de-rated for reflective/absorbing substrates (e.g. ~0.5× the Si dose on Au).

07 / Sources

Sources & disclaimer

  • micro resist technologyma-N 1420 datasheet (micro resist technology 'Processing guidelines — Negative Tone Photoresist Series ma-N 1400', document code ls.05.11.25.02 (no separate calendar date printed on the document; also mirrored as vh_man_1400_en_05112502_ls.pdf)) · accessed 2026-07-10
  • https://www.microresist.de/en/produkt/ma-d-533-s/ — used only to confirm that the ma-D 533/S developer is TMAH-based (the primary ma-N 1400 datasheet only says 'aqueous alkaline development' without naming the base) — fills the developerFamily field, not a numeric process source
Research using this resist
  1. Thoen et al.. Combined ultraviolet- and electron-beam lithography with Micro-Resist-Technology GmbH ma-N1400 resist. Journal of Vacuum Science & Technology B (2022). doi:10.1116/6.0001918
    one ma-N 1400 layer exposed by UV and 100 kV e-beam for an on-chip THz spectrometer

Manufacturer datasheet values are starting points; optimal parameters depend on your substrate, equipment and environment. Product names and trademarks belong to their respective owners. NANYTE is not affiliated with the manufacturers listed. Last updated 2026-07-12.

Cite this recipe

NANYTE. "ma-N 1420 process recipe." NANYTE Photoresist Library. https://nanyte.com/photoresists/ma-n-1420. Accessed 2026-07-12.

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