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AZ P4620 process recipe

AZ P4620 is a thick, single-coat DNQ-novolak positive photoresist from the AZ P4000 series, demonstrated in this datasheet for copper and gold electroplating molds at film thicknesses from roughly 12 to 28 µm.

https://nanyte.com/photoresists/az-p4620 · last updated 2026-07-10

At a glance
Manufacturer
AZ Electronic Materials
Tone
positive
Chemistry
DNQ-novolak
Thickness
6.9–14.8 µm
Developer
AZ 400K
Applications
Electroplating / molding

Unverified — not yet human-checked; values transcribed from the datasheet, characterize on-tool.

01 / Coating

Spin coating

AZ P4620 is spin-coated to 6.9–14.8 µm. The curve below is redrawn from the manufacturer's published data — read your target thickness off the vertical axis and take the matching spin speed as a starting point.

Spin curve for AZ P4620: film thickness in µm against spin speed in rpm.0.005.01015201k2k3k4kSPIN SPEED (rpm)THICKNESS (µm)
Data points
AZ P4620 — film thickness (µm) by spin speed (rpm)
Seriesrpmµm
AZ P4620 as supplied100015
150012
200010
25008.9
30008.0
35007.4
40006.9

Values are the manufacturer's starting points, not a guarantee; verify on your own tool. Characterize on-tool. Series digitized from a published figure were independently cross-checked by a second blind read; treat those values as approximate (±10 %).

read from figure, "AZ® P4620 Spin Speed Curve", p.26 of AZ P4620 Photoresist Data Package — single-product chart with one plotted series (unambiguous), softbake 110°C/180 s hotplate on 150 mm Si

Redrawn from the manufacturer's published data — hover to read values between points, click to pin.

Curve conditions per p.26: 150 mm silicon substrate, softbake 110°C/180 s hotplate. A separate multi-grade comparison chart (p.27, a lower-resolution scanned image) plots P4620 alongside P4903, P4400, P4330-RS, P4210 and P4110; at matching speeds it reads noticeably higher (~16.5 µm at 1000 rpm vs. 14.8 µm on the dedicated p.26 chart, an ~11% disagreement between the two figures in the same document). The p.26 chart was used as the published curve because it is the higher-precision, single-product source with unambiguous curve identity; the p.27 chart is noted here only as an internal-consistency flag for QC. No dispense volume, spin ramp, or edge-bead detail is published anywhere in this document.

Adhesion
HMDS not required — No HMDS or other adhesion-promoter step is mentioned anywhere in this datasheet.
Rehydration
A 60-minute rehydration wait is specified after the two-stage softbake (100°C/500 s hotplate, then 90°C/180 min oven) in the 28 µm single-coat gold-plating process, before exposure. (Source: AZ® P4620 Gold Plating Process, p.7 of AZ P4620 Photoresist Data Package)
02 / Bake

Soft bake

Soft bake
110 °C · 3 min · hotplate
Notes
This is the most consistently repeated single-recipe softbake in the document (15 µm copper-plating process, p.4-6, and matches the spin-curve conditions on p.26). Other film thicknesses in this same datasheet use different bakes: 12 µm at 110°C/80 s (p.10, p.13-17); a two-layer 24 µm coat at 110°C/80 s then 115°C/180 s (p.18-21); 17 µm at 120°C/240 s (p.22); and the 28 µm single-coat process at 100°C/500 s hotplate then 90°C/180 min oven, followed by a 60-minute rehydration wait (p.7-9, see rehydration field). Softbake is thickness- and tool-dependent; no single value applies to all P4620 processes.

SOURCE: p.4-6 of AZ P4620 Photoresist Data Package (AZ P4620 Copper plating process conditions)

03 / Exposure

Exposure dose

The manufacturer does not publish a clearing dose for AZ P4620. Determine it with a dose array on your own tool.

As published
ghi-line / gh-line exposure (broadband, includes g-, h- and i-line together) — Canon PLA-501F ghi-line contact aligner (p.4-9, p.22), Ultratech 1500 gh-line stepper (p.10-21). Not restricted to i-line 365 nm or h-line 405 nm alone.

Not published for this resist: Dose at 365 nm, Dose at 405 nm — characterize on-tool.

04 / Development

Development

Developer
AZ 400K
Dilution
1:4
Time
5 min
Method
immersion
Rinse
Not published — characterize on-tool
Developer family
Buffered alkaline

SOURCE: AZ P4620 Copper plating process conditions, p.4-6 of AZ P4620 Photoresist Data Package (AZ 400K 1:4, immersion 300 s, 23°C)

05 / Post-processing

Hard bake, etch & strip

Not published for this resist: Hard bake, Descum, Etch resistance, Stripper, Storage — characterize on-tool.

06 / Applications

Where it's used

Electroplating / molding

AZ P4620 is a DNQ-novolak (diazonaphthoquinone/novolak) positive resist from AZ's thick-film P4000 series, positioned in this datasheet for copper and gold electroplating molds rather than lift-off or etch masking. It develops in AZ 400K (a buffered, metal-ion-containing alkaline developer — the datasheet's own preferred choice) or, for finer-pitch stepper lithography, in AZ 300 MIF (TMAH, metal-ion-free). Softbake, exposure dose and develop time all scale with film thickness rather than following one fixed recipe: a 12 µm coat baked at 110°C/80 s takes roughly 900 mJ/cm² on a gh-line stepper, while a 24 µm two-layer coat (110°C/80 s then 115°C/180 s) needs roughly 1650-1950 mJ/cm². The 28 µm single-coat gold-plating process is the process worth flagging for a first-time user: it uses a two-stage softbake (100°C/500 s hotplate, then 90°C/180 min oven) followed by a 60-minute rehydration wait before exposure — a classic thick-DNQ step that is easy to skip and, if skipped, tends to cause scumming or adhesion failure at develop. As a non-chemically-amplified DNQ resist it needs no post-exposure bake.

07 / Sources

Sources & disclaimer

Manufacturer datasheet values are starting points; optimal parameters depend on your substrate, equipment and environment. Product names and trademarks belong to their respective owners. NANYTE is not affiliated with the manufacturers listed. Last updated 2026-07-10.

Cite this recipe

NANYTE. "AZ P4620 process recipe." NANYTE Photoresist Library. https://nanyte.com/photoresists/az-p4620. Accessed 2026-07-10.

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