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AZ 10XT process recipe

AZ 10XT is a thick positive-tone DNQ photoresist for plating molds and etch masks, sold in 520/220/100 cP grades for single-coat films from 4 µm to over 20 µm — a thick-DNQ line that needs a 30–60 min post-softbake rehydration wait on films above 5 µm.

https://nanyte.com/photoresists/az-10xt · last updated 2026-07-26

At a glance
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Manufacturer
Merck
Tone
positive
Chemistry
DNQ-novolak
Thickness
4–20 µm
Exposure dose
380 mJ/cm² at 365 nm
Developer
AZ 400K
Applications
Electroplating / molding · Etch mask

Cross-checked — two independent extractions agree on the spin curve and the single-value figures.

The exposed resist dissolves in the developer; the unexposed film stays. Schematic cross-sections for AZ 10XT — feature width, film aspect ratio and sidewall angle are illustrative, not to scale.
01 / Coating

Spin coating

Spin curves for AZ 10XT: film thickness in µm against spin speed in rpm.0510151k1.5k2k2.5k3kSPIN SPEED (rpm)THICKNESS (µm)
Data points
AZ 10XT — film thickness (µm) by spin speed (rpm)
SeriesrpmµmPublished dose
AZ 10XT 520cP100014
150012
200010
25009.0
30007.8
AZ 10XT 220cP10009.8
15007.7
20006.6
25005.9
30005.3
AZ 10XT 100cP10006.7
15005.6
20005.0
25004.4
30004.0

Values are the manufacturer’s starting points, not a guarantee — characterize on your own tool. Series digitized from a published figure are approximate (±10 %).

Published dose is the datasheet’s own thickness bracket, quoted as printed — the full table and its citation are in the exposure section. A thickness the table does not cover shows nothing, and a thickness within 10 % of a bracket edge shows every bracket it could fall in.

AZ 10XT 520cP: read from figure, "SPIN CURVES (200MM SILICON)", p.1 of AZ 10XT Series Technical datasheet (Rev. 03/21) — one of three viscosity-grade curves on the same chart, identified by its red 520cP legend entry

AZ 10XT 220cP: read from figure, "SPIN CURVES (200MM SILICON)", p.1 of AZ 10XT Series Technical datasheet (Rev. 03/21) — identified by its blue 220cP legend entry; consistent with the '220cps, 6µm thick film' reference process elsewhere in this document (p.3-4, p.6-7)

AZ 10XT 100cP: read from figure, "SPIN CURVES (200MM SILICON)", p.1 of AZ 10XT Series Technical datasheet (Rev. 03/21) — identified by its green 100cP legend entry

3 series redrawn from the manufacturer's published data — hover to read between points, click to pin.
  • Spin curves cover 1000-3000 rpm on 200 mm silicon for three viscosity grades (520 cP, 220 cP, 100 cP), each a single, unambiguously legended line on one chart (not a multi-SKU chart, so no grade-identification ambiguity) — values above are read from the figure, not a published numeric table, and need visual QC.
  • Coating note (p.12): the spin-curve graphs assume coating to equilibrium
  • thicker coats can be produced off-curve by shortening spin time and letting the film 'self level', which this document does not quantify.
  • No dispense volume, spin ramp, or edge-bead detail is published anywhere in this datasheet.
Adhesion
HMDS recommended — Oxide-forming substrates (e.g. Si) should be HMDS primed prior to coating AZ 10XT (PROCESS CONSIDERATIONS > SUBSTRATE PREPARATION, p.12).
Rehydration
A rehydration delay of 30-60 minutes between soft bake and exposure is required for films thicker than 5.0 µm; delay time varies with film thickness and ambient humidity. The front-page process summary lists a 30-minute rehydration hold as the typical value, and the 6 µm and 12 µm reference processes each specify a 30-minute 'Post Bake Delay'; the 24 µm double-coat reference process uses a 45-minute delay.1
02 / Bake

Soft bake

Soft bake
110 °C (95–110 °C) · 2 min · hotplate
Notes
This is the reference 6 µm-film softbake, repeated identically across all four 6 µm reference processes (dense lines and holes, on Si and on Cu; p.3, p.4, p.6, p.7). The datasheet states soft bake time is 'film thickness dependent' (p.1) and that AZ 10XT soft bake temperature should generally be in the 95-110°C range (p.12, PROCESS CONSIDERATIONS > SOFT BAKE), with ramped temperatures possibly needed for very thick films to avoid solvent-outgassing bubbles. Other documented thicknesses use different bakes: 12 µm at 110°C/180 s (p.9); a 24 µm double coat at 110°C/80 s (first layer) then 115°C/180 s (second layer) (p.10).

SOURCE: Reference Process tables, p.3-4 and p.6-7 of AZ 10XT Series Technical datasheet (Rev. 03/21) (6 µm film on Si/Cu)

03 / Exposure

Exposure dose

The manufacturer publishes 380 mJ/cm² at 365 nm. Dose scales with film thickness and depends on your optics, so treat it as a starting point and run a dose array.

Dose at 365 nm
380 mJ/cm²
Dose at 405 nm
Not published — characterize on-tool
As published
380 mJ/cm² i-line is the datasheet's 6 µm-on-silicon figure; the same film on copper needs more, and a 24 µm double coat took 1785 and 1875 mJ/cm² on two g-h-line tools.

SOURCE: Reference Process tables, p.3-4 of AZ 10XT Series Technical datasheet (Rev. 03/21)

AZ 10XT — dose by film thickness · at 365 nm · dense lines, 6 µm film on copper
Film thicknessDose
6 µm455 mJ/cm²
SOURCE: REFERENCE PROCESS (DENSE LINES IN 6µM FILM THICKNESS ON CU)…

REFERENCE PROCESS (DENSE LINES IN 6µM FILM THICKNESS ON CU), p.6 of AZ 10XT Series Technical datasheet (Rev. 03/21): "i-line @ 455mJ/cm2 nominal (0.48NA)". i-line is the 365 nm mercury line.

AZ 10XT — dose by film thickness · at 365 nm · contact holes, 6 µm film on copper
Film thicknessDose
6 µm445 mJ/cm²
SOURCE: REFERENCE PROCESS (HOLES IN 6.0µM FILM THICKNESS ON CU), p.7…

REFERENCE PROCESS (HOLES IN 6.0µM FILM THICKNESS ON CU), p.7 of AZ 10XT Series Technical datasheet (Rev. 03/21): "i-line @ 445mJ/cm2 nominal (0.48NA)". i-line is the 365 nm mercury line.

04 / Development

Development

Developer
AZ 400K
Dilution
1:4
Time
7 min
Method
immersion
Rinse
Not published — characterize on-tool
Developer family
TMAH or buffered alkaline
SOURCE: Reference Process tables (dense lines / holes, 6 µm film, Si…

Reference Process tables (dense lines / holes, 6 µm film, Si and Cu), p.3-4 and p.6-7 of AZ 10XT Series Technical datasheet (Rev. 03/21)

05 / Post-processing

Hard bake, etch & strip

Hard bake
90–100 °C
Stripper
AZ Kwik Strip, AZ 300T, or AZ 400T (solvent-based removers), per PROCESS CONSIDERATIONS > STRIPPING, p.12 of AZ 10XT Series Technical datasheet

Not published for this resist: Descum, Etch resistance, Storage — characterize on-tool.

SOURCE: PROCESS CONSIDERATIONS > HARD BAKE, p.12 of AZ 10XT Series Technical datasheet (Rev. 03/21)

06 / Applications

Where it's used

Practical notes from the datasheet

AZ 10XT is a thick positive-tone plating resist pitched by the vendor as an upgrade over conventional thick DNQ resists in sidewall profile, aspect ratio and photospeed. Like other thick DNQ-class positive resists it needs a rehydration wait — 30-60 minutes between soft bake and exposure for any film over 5 µm — before it develops reliably; skipping it is a common source of process trouble on thick coats, and the wait grows to 45 minutes for the datasheet's 24 µm double-coat process. Post-expose bake is explicitly optional and every reference process in this datasheet runs with none, consistent with a non-chemically-amplified resist. It develops in either TMAH (AZ 300MIF/AZ 435MIF) or a buffered alkaline developer (AZ 400K, used in most of the reference processes here) — the datasheet does not name one as preferred. HMDS priming is called out explicitly for oxide-forming substrates such as silicon. Exposure dose and softbake time both scale sharply with target film thickness and substrate: at the same 6 µm film thickness the i-line nominal rises from 380 mJ/cm² on silicon to 445-455 mJ/cm² on copper, so confirm the working dose on your own tool. A first-time user should follow the specific reference-process table for their target thickness and substrate rather than a single rule of thumb.

07 / Sources

Sources & disclaimer

Cited above
  1. FILM REHYDRATION, p.12, and TYPICAL PROCESS (p.1) / Reference Process tables (p.3-4, p.6-7, p.9-10) of AZ 10XT Series Technical datasheet (Rev. 03/21)
Research using this resist
  1. Schermer et al.. High-resolution projection lithography for MEMS-applications using thick photoresist AZ 10XT. 2022 Smart Systems Integration (SSI) (2022). doi:10.1109/SSI56489.2022.9901437
    Thick AZ 10XT under projection (stepper) lithography for MEMS etch masks

Manufacturer datasheet values are starting points; optimal parameters depend on your substrate, equipment and environment. Product names and trademarks belong to their respective owners. NANYTE is not affiliated with the manufacturers listed. Last updated 2026-07-26.

Cite this recipe

NANYTE. "AZ 10XT process recipe." NANYTE Photoresist Library. https://nanyte.com/photoresists/az-10xt. Accessed 2026-07-26.

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BEAM exposes at 365 nm, the wavelength this resist's datasheet specifies a dose for, and it resolves >10:1 aspect ratios in thick resist.

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