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AZ 9245 process recipe

AZ 9245 is the thinner (220 cP) of two viscosity grades in Clariant/AZ Electronic Materials' AZ 9200 high-resolution thick-resist line, coating to roughly 4.6-6.6 µm and resolving sub-micron lines and spaces at 4.6 µm film thickness, targeted at coil-plating and thin-film recording-head applications.

https://nanyte.com/photoresists/az-9245 · last updated 2026-07-10

At a glance
Manufacturer
AZ Electronic Materials (Clariant AG)
Tone
Not photoimageable (underlayer)
Thickness
4.6–6.6 µm
Exposure dose
900 mJ/cm²
Developer
AZ 400K Developer
Applications
Electroplating / molding · High aspect ratio · MEMS structural

Cross-checked — two independent extractions agree.

01 / Coating

Spin coating

AZ 9245 is spin-coated to 4.6–6.6 µm. The curve below is redrawn from the manufacturer's published data — read your target thickness off the vertical axis and take the matching spin speed as a starting point.

Spin curve for AZ 9245: film thickness in µm against spin speed in rpm.0.002.04.06.02k2.5k3k3.5k4kSPIN SPEED (rpm)THICKNESS (µm)
Data points
AZ 9245 — film thickness (µm) by spin speed (rpm)
Seriesrpmµm
AZ 9245 (220 cP)20006.6
25005.8
30005.2
35004.8
38004.6

Values are the manufacturer's starting points, not a guarantee; verify on your own tool. Characterize on-tool.

numeric table "Film Thickness" (columns 2000/2500/3000/3500 rpm, row "AZ 9245 Photoresist 220 cP"), p.7, combined with the single grade-specific anchor point from "Typical Process for 4.6 µm Film Thickness [AZ 9245 Photoresist (220 CPS)]" (Coat: Spin 3800 rpm, 60 sec → 4.6 µm target), p.6, of AZ 9200 Photoresist datasheet. Both are explicitly labeled AZ 9245 (220 cP) and are mutually consistent (monotonic decrease: 4.8 µm at 3500 rpm to 4.6 µm at 3800 rpm).

Redrawn from the manufacturer's published data — hover to read values between points, click to pin.

IMPORTANT UNIT FLAG FOR QC: the p.7 table's units render ambiguously across two extraction passes of the same page — one pass shows the values with an "Å" (Angstrom) suffix (e.g. "6 600 Å"), another shows the same figures as "6.6um" etc. A literal Angstrom reading (0.66 µm at 2000 rpm) would be physically inconsistent with the rest of the document: it would mean the film gets THICKER at the higher 3800 rpm point (4.6 µm, from the p.6 Typical Process table) than at the lower 2000 rpm point (0.66 µm), which violates basic spin-coating physics (thickness decreases with increasing spin speed). The µm reading is internally consistent with the 4.6 µm/3800 rpm anchor point and is used here, but a QC reviewer should confirm the actual printed unit glyph against the source PDF. Coat/dispense and edge-bead removal are documented as explicit process steps for this grade (p.6): "Coat: Dispense static or dynamic @ 300 rpm, Spin 3800 rpm/60 sec" then "Edge Bead Removal: Rinse 500 rpm/10 sec, Dry 1000 rpm/10 sec" — both built into the same Typical Process table as softbake/exposure/develop. No rehydration hold is listed anywhere in this document (see the rehydration field) — despite this being a thick resist, where a rehydration hold is sometimes expected, this specific 1997 datasheet's process tables simply do not include one.

Adhesion
HMDS not required — Not addressed anywhere in this datasheet — no substrate priming/HMDS guidance is given at all, unlike the Merck-era AZ documents processed alongside this one.
Rehydration
Not mentioned anywhere in this document. The grade-specific "Typical Process for 4.6 µm Film Thickness [AZ 9245 Photoresist (220 CPS)]" table (p.6) lists Coat → Softbake → Edge Bead Removal → Exposure → Post Exposure Bake (not recommended) → Development, with no separate rehydration step. This may be a gap in this particular 1997 datasheet rather than confirmation the process needs none — not used as a basis to assert either way; flagged for QC.
02 / Bake

Soft bake

Soft bake
110 °C · 2 min · hotplate
Notes
Grade-specific: "Softbake 110°C, 120 sec hotplate" — Typical Process for 4.6 µm Film Thickness [AZ 9245 Photoresist (220 CPS)], p.6. Corroborated by matching "Softbake Hotplate 110°C, 120 sec" conditions on the Linearity [Broadband] and Focus Latitude [Broadband] test panels for the same 4.6 µm film thickness (p.2-3).

SOURCE: Typical Process for 4.6 µm Film Thickness [AZ 9245 Photoresist (220 CPS)], p.6 of AZ 9200 Photoresist datasheet.

03 / Exposure

Exposure dose

The manufacturer publishes 900 mJ/cm² ("Exposure (10% bias) 900 mJ/cm2, broadband stepper" — Typical Process for 4.6 µm Film Thickness [AZ 9245 Photoresist (220 CPS)], p.6. The document separately states AZ 9200 has "sensitivity to both h- and i-line" and is "capable for both broadband and i-line steppers" (p.1), but this specific grade's documented process dose is broadband.). Dose scales with film thickness and depends on your optics, so treat it as a starting point and run a dose array.

As published
"Exposure (10% bias) 900 mJ/cm2, broadband stepper" — Typical Process for 4.6 µm Film Thickness [AZ 9245 Photoresist (220 CPS)], p.6. The document separately states AZ 9200 has "sensitivity to both h- and i-line" and is "capable for both broadband and i-line steppers" (p.1), but this specific grade's documented process dose is broadband.

Not published for this resist: Dose at 365 nm, Dose at 405 nm — characterize on-tool.

SOURCE: Typical Process for 4.6 µm Film Thickness [AZ 9245 Photoresist (220 CPS)], p.6; corroborated by Linearity [Broadband] and Focus Latitude [Broadband], p.2-3, of AZ 9200 Photoresist datasheet.

04 / Development

Development

Developer
AZ 400K Developer
Dilution
1:4
Time
2 min
Method
spray
Rinse
Spin rinse 300 rpm/20 sec, then spin dry 4000 rpm/15 sec (following the AZ 400K spray develop at 27°C dispense temperature).
Developer family
Buffered alkaline

SOURCE: Typical Process for 4.6 µm Film Thickness [AZ 9245 Photoresist (220 CPS)], p.6 of AZ 9200 Photoresist datasheet.

05 / Post-processing

Hard bake, etch & strip

Stripper
AZ 400T and 300T strippers are recommended for removal of AZ 9200 photoresist; AZ S-46 stripper is a non-NMP solvent stripper particularly suited to thin film recording head applications (Companion Products, p.8).
Storage
"Keep in sealed original container. Protect from light and heat. Store between 30 and 70°F (–1 to 24°C). Refrigerate whenever possible. Refrigeration may extend shelf life. Empty container may contain harmful residue and vapors." (Storage, p.8).

Not published for this resist: Hard bake, Descum, Etch resistance — characterize on-tool.

06 / Applications

Where it's used

Electroplating / moldingHigh aspect ratioMEMS structural

AZ 9245 (220 cP) is the thinner of two viscosity grades in this 1997 Clariant AZ 9200 thick-resist line, targeting a 4.6 µm single-coat film with sub-micron resolution (<1 µm lines/spaces per p.1) and 5-7:1 aspect ratios on broadband steppers. Its Typical Process table explicitly states PEB is "not recommended in most applications" and does not list a rehydration-hold step at all — contrary to what might be assumed for a thick resist, this document gives no basis to include one. Edge-bead removal is documented as an explicit spin-rinse/spin-dry step (500 rpm/10s rinse, 1000 rpm/10s dry) built directly into the same process table as coat, softbake, exposure, and develop. The document states AZ 9200 is sensitive to both h- and i-line light, but only broadband exposure data (900 mJ/cm² nominal) is actually published for the 4.6 µm/AZ 9245 process specifically — the datasheet's only i-line dose data belongs to the thicker AZ 9260 (10 µm) grade and is not reused here. This document predates and differs structurally from the Merck-branded AZ datasheets processed alongside it (no explicit tone/chemistry statement, no HMDS guidance), so tone and chemistry are left unset rather than inferred from sibling documents or general familiarity with the product family.

07 / Sources

Sources & disclaimer

Manufacturer datasheet values are starting points; optimal parameters depend on your substrate, equipment and environment. Product names and trademarks belong to their respective owners. NANYTE is not affiliated with the manufacturers listed. Last updated 2026-07-10.

Cite this recipe

NANYTE. "AZ 9245 process recipe." NANYTE Photoresist Library. https://nanyte.com/photoresists/az-9245. Accessed 2026-07-10.

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