Skip to content

AZ 125nXT process recipe

AZ 125nXT is a photopolymer negative-tone photoresist for ultra-thick single-coat films (roughly 18-120 µm across its two viscosity grades), built for Cu/Au/solder electroplating and RIE etch masks in advanced packaging, with no rehydration hold and no PEB required.

https://nanyte.com/photoresists/az-125nxt · last updated 2026-07-26

At a glance
Download PDF
Manufacturer
Merck
Tone
negative
Chemistry
Photopolymer
Thickness
18–120 µm
Developer
AZ 300MIF
Applications
Etch mask · Electroplating / molding · High aspect ratio

Cross-checked — two independent extractions agree on the spin curve and the single-value figures.

The exposed resist stays after development; the unexposed film dissolves. Schematic cross-sections for AZ 125nXT — feature width, film aspect ratio and sidewall angle are illustrative, not to scale.
01 / Coating

Spin coating

Spin curves for AZ 125nXT: film thickness in µm against spin speed in rpm.0501001501k1.5k2k2.5k3kSPIN SPEED (rpm)THICKNESS (µm)
Data points
AZ 125nXT — film thickness (µm) by spin speed (rpm)
Seriesrpmµm
AZ 125nXT-10B600120
800100
100075
150055
190048
210043
250038
AZ 125nXT-7B60057
100035
130024
150021
190018
230014

Values are the manufacturer’s starting points, not a guarantee — characterize on your own tool. Series digitized from a published figure are approximate (±10 %).

AZ 125nXT-10B: read from figure, p.10 of AZ 125nXT Series Technical Datasheet (Merck, Rev. 01/24), 'COATING GUIDELINES' spin-speed chart. Two-grade chart; traces identified by the chart's own legend (filled triangle = AZ 125nXT-10B, filled circle = AZ 125nXT-7B), not by color alone.

AZ 125nXT-7B: read from figure, p.10 of AZ 125nXT Series Technical Datasheet (Merck, Rev. 01/24), 'COATING GUIDELINES' spin-speed chart. Two-grade chart; traces identified by the chart's own legend (filled triangle = AZ 125nXT-10B, filled circle = AZ 125nXT-7B), not by color alone.

2 series redrawn from the manufacturer's published data — hover to read between points, click to pin.
  • The datasheet explicitly cautions (p.10) that, unlike thin-resist spin curves, 'films will continue to thin with extended spin times' for a resist this viscous, and that the plotted curves 'may be used as general guidelines for coating films of 30µm thickness and above' - i.e. the document itself flags the low-thickness end of its own chart as unreliable.
  • That caveat is directly visible in the data: my read of the AZ 125nXT-7B trace extends from ~57 µm (600 rpm) down to ~14 µm (2300 rpm), both outside the grade's own stated 18-35 µm range (p.2 THICKNESS GRADES table) - an internal inconsistency a QC reviewer should note, not something I resolved.
  • A full example coating sequence with acceleration and function-per-step (dispense/spread/snap-spin/set-thickness/backside rinse-dry/edge-bead-flatten) is given on p.10 for building a real recipe, rather than a single spin-speed number.
Adhesion
HMDS recommended — 'Oxide forming substrates (Si, etc.) should be HMDS primed prior to coating AZ 125nXT. Contact your product representative for detailed information on pre-treating with HMDS.' (p.11, Substrate Preparation).
Rehydration
None required - the datasheet states explicitly, in both the Typical Process summary ('Rehydration Hold: None', p.1) and in bold in the Process Considerations section ('NO POST BAKE REHYDRATION DELAYS ARE REQUIRED', p.11), that no rehydration hold is needed, unlike thick DNQ resists.
02 / Bake

Soft bake

Soft bake
115–140 °C · 5–20 min
Notes
Soft-bake conditions are 115-140°C for 5-20 min, and the time scales with film thickness. The published examples span the whole window: 115°C stepping-proximity bake, up to 120 s at a 0.002 in gap, for 20 µm of the 7B grade; 130°C for 13 min on a hotplate for 50 µm of 10B; 120°C stepping-proximity, up to 400 s in contact, for 20 µm of 7B on a different tool; 135°C for 25 min for 120 µm of 10B.

SOURCE: p.1, p.11 (range); pp.3-6 (worked-example values)

03 / Exposure

Exposure dose

Sensitivity spans 365 to 435 nm with no single stated dose, and the tool matters as much as the film: one 20 µm coat took 1120 mJ/cm² on a Suss MA-200 and 2000 mJ/cm² on an Ultratech AP300; a 70 µm film took 1800 mJ/cm². Run a dose array on your own tool to land the working dose.

Not published for this resist: Dose at 365 nm, Dose at 405 nm — characterize on-tool.

04 / Development

Development

Developer
AZ 300MIF
Dilution
0.26N (2.38%) TMAH, ready-to-use; puddle mode recommended
Method
puddle
Developer family
TMAH-based

Not published for this resist: Time, Rinse — characterize on-tool.

SOURCE: p.1, p.11 (developer/mode); pp.3-6 (worked-example times)

05 / Post-processing

Hard bake, etch & strip

Hard bake
130–140 °C
Etch resistance
Described only qualitatively: 'etch resistance, chemical resistance, and thermal stability far superior to typical chemically amplified photoresists' (p.1) and 'RIE etch applications' (p.1). No etch rate or selectivity number is given anywhere.
Stripper
AZ 400T, 75°C, 20-25 min with agitation (p.11, Stripping); corroborated by worked electroplating examples: 'Strip: AZ 400T @ 75C' for Cu (p.7) and 'Photoresist Strip AZ 400T @ 75°C' for Au (p.8)

Not published for this resist: Descum, Storage — characterize on-tool.

SOURCE: p.11 (Hard Bake)

06 / Applications

Where it's used

Practical notes from the datasheet

AZ 125nXT is a photopolymer (not conventional DNQ or the vendor's own 'typical' CAR) negative resist purpose-built for ultra-thick, high-aspect-ratio plating molds and RIE masks up to and beyond 100 µm in a single coat. Two properties make it distinct from thinner thick-film resists: no rehydration hold is needed after softbake, and a PEB is explicitly not required at all - both are called out in bold in the datasheet, in direct contrast to the classic DNQ rehydration wait this recipe library flags elsewhere. Real electroplating results are documented for Cu, Ni-compatible, and Au processes with post-plate/post-strip micrographs (pp.7-8), and the stripped resist shows no reported underplating. Coating this resist is its own discipline: the vendor explicitly warns that, unlike thin-resist spin coating, films keep thinning with extended spin time, so both spin speed and spin time must be tuned together (p.10), and the datasheet's own coating-guideline curves are only endorsed for films of 30 µm and above even though they are plotted further down. HMDS priming is required on oxide-forming substrates such as Si.

07 / Sources

Sources & disclaimer

Research using this resist
  1. Staab et al.. Applications of Novel High-Aspect-Ratio Ultrathick UV Photoresist for Microelectroplating. Journal of Microelectromechanical Systems (2011). doi:10.1109/jmems.2011.2159098
    The acrylic resist AZ 125 nXT is demonstrated at 400, 800 and 1400 um film thickness with 20:1 aspect ratio for low-cost UV-LIGA, electroformed in acid copper at room temperature and near-neutral nickel at 50 C, then stripped in DMSO/acetone or plasma to release freestanding metal at 13:1 and 16:1.
  2. Knoll et al.. Fabrication of microfluidic chips using lithographic patterning and adhesive bonding of the thick negative photoresist AZ 125 nXT. Proceedings of SPIE (2015). doi:10.1117/12.2178812
    AZ 125 nXT was lithographically patterned into 90 um deep microfluidic channels and sealed by adhesive bonding, presented as an SU-8 alternative that fully cross-links during UV exposure without a post-exposure bake.

Manufacturer datasheet values are starting points; optimal parameters depend on your substrate, equipment and environment. Product names and trademarks belong to their respective owners. NANYTE is not affiliated with the manufacturers listed. Last updated 2026-07-26.

Cite this recipe

NANYTE. "AZ 125nXT process recipe." NANYTE Photoresist Library. https://nanyte.com/photoresists/az-125nxt. Accessed 2026-07-26.

Ready to run this process on your own tool?Talk to an engineer →

Expose it at 365 and 405 nm

NANYTE BEAM is a desktop maskless lithography system with software-selectable dual-wavelength exposure and 16-bit grayscale — no photomask, no mask cost, same-day iteration.

What is NANYTE BEAM?

Improve this recipe

Run this resist in your lab? Send us what actually works, or flag a value that's wrong. No account, no email needed — a handle and affiliation are optional and become your credit line. Every contribution is checked against published sources before it appears.